HomeMy WebLinkAbout09911-01-0 - Paint Product Data - reviewed by PBA - AProduct Submittal
OXOBOXO LOFTS
Presented By:
Richard Bolbrock
Sales Representative
(860) 289-0814
richard.bolbrock@sherwin.com
SHERWIN-WILLIAMS
1197 FARMINGTON AVE
BRISTOL, CT 06010 4751
(860) 589-8804
February 24, 2020
Product Submittal
Project:OXOBOXO LOFTS
CT
Dear Pete Kite:
Thank you for considering Sherwin-Williams products for the OXOBOXO
LOFTS project. Included in this package is the Sherwin-Williams submittal
for the above referenced project.
Should you require assistance or have any questions or concerns, please
contact me at (860) 983-7671 or e-mail me at richard.bolbrock@sherwin.com.
Richard Bolbrock
Sales Representative
(860) 289-0814
richard.bolbrock@sherwin.com
SHERWIN-WILLIAMS
1197 FARMINGTON AVE, BRISTOL, CT 06010 4751
1
Interior Finishes
Wood Ceilings
Primer: B51W00620 - PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
Finish: B30W12651 - PM 200 0 FL
GWB Ceilings
Finish: B30W12651 - PM 200 0 FL
GWB Walls
Primer: B28W02600 - ProMar® 200 Zero VOC Interior Latex Primer
Finish: B20W12651 - ProMar® 200 Zero VOC Interior Latex Eg-Shel
Wood Trim
Finish: B31W01951 - PM 200 HP 0 SG
Doors
Finish: B31W01951 - PM 200 HP 0 SG
Ferrous Metal
Spot Prime: B66W01310 - PI PROCRYL PR
Finish: B66W00651 - Pro Industrial High Performance Acrylic - Semi-Gloss
Structural Steel/Trusses
Primer: B66W01310 - PI PROCRYL PR
Finish: B30W12651 - PM 200 0 FL
Interior Brick & Masonry Substrates
Primer: LX02W0050 - LXN C&M PRIMER
Finish: B20W12651 - ProMar® 200 Zero VOC Interior Latex Eg-Shel
Concrete Floor Sealer
Finish: CF31T0007 - CNFLX SILOXANE
Exterior Finishes
Exterior Trim
Primer: B51W00620 - PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
Finish: A89W01151 - SuperPaint® Exterior Latex Satin
OXOBOXO LOFTS
February 24, 2020
Basic Surface Preparation
Coating performance is directly affected by surface preparation. Coating integrity and service life will be reduced because of
improperly prepared surfaces. As high as 80% of all coating failures can be directly attributed to inadequate surface preparation
that affects coating adhesion. Proper product selection, surface preparation, and application affect coating performance. Coating
integrity and service life will be reduced because of improperly prepared surfaces. Selection and implementation of proper
surface preparation ensures coating adhesion to the substrate and prolongs the service life of the coating system.
The majority of paintable surfaces are concrete, ferrous metal, galvanizing, wood and aluminum. They all require protection to
keep them from deteriorating in aggressive environments. Selection of the proper method for surface preparation depends on
the substrate, the environment, the coating selected, and the expected service life of the coating system. Economics, surface
contamination, and the effect on the substrate will also influence the selection of surface preparation methods. Recognize that
any surface preparation short of total removal of the old coating may compromise the service length of the system.
Verify the existence of lead based paints on the project. Buildings constructed after 1978 are less likely to contain lead based
paints. If lead based paints are suspected on the project, all removal must be done in accordance with the EPA Renovation,
Repair and Painting and all applicable state and local regulations. State and local regulations may be more strict than those set
under the federal regulations. Verify that Owner has completed a Hazardous Material Assessment Report for the project prior to
issuing of Drawings. Concluding that no lead based paints were found on project site, delete paragraph regarding lead based
paints.
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure
to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women.
Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly
fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead
Information Center at 1-800-424-LEAD (in US) or contact your local health authority. Removal must be done in accordance
with EPA Renovation, Repair and Painting Rule and all related state and local regulations. Care should be taken to follow all
state and local regulations which may be more strict than those set under the federal RRP Rule.
No exterior painting should be done immediately after a rain, during foggy weather, when rain is predicted, or when the
temperature is below 50°F, unless the products to be used are designed to be used in those environments.
_______________
Aluminum – S-W 1: Remove all oil, grease, dirt, oxide and other foreign material by cleaning per SSPC-SP1, Solvent
Cleaning.
Block (Cinder and Concrete) – S-W 3: Remove all loose mortar and foreign material. Surface must be free of laitance,
concrete dust, dirt, form release agents, moisture curing membranes, loose cement, and hardeners. Concrete and mortar must be
cured at least 28 days at 75°F. The pH of the surface should be between 6 and 9. On tilt-up and poured-in-place concrete,
commercial detergents and abrasive blasting may be necessary to prepare the surface. Fill bug holes, air pockets, and other
voids with a cement patching compound (per ASTMD4261).
Brick – S-W 4: Must be free of dirt, loose and excess mortar, and foreign material. All brick should be allowed to weather for
at least one year followed by wire brushing to remove efflorescence. Treat the bare brick with one coat of Loxon Conditioner.
Concrete and Masonry – Concrete, Poured – Exterior or Interior– S-W 5: The preparation of new concrete surfaces is as
important as the surface preparation of steel. The following precautions will help assure maximum performance of the coating
system and satisfactory coating adhesion:
1. Cure – Concrete must be cured prior to coating. Cured is generally defined as concrete poured and aged at a material
temperature of at least 75°F for at least 28 days unless specified products are designed for earlier application.
2. Moisture – Reference ASTM F1869-98 Moisture Test by use of Calcium Chloride or ASTM D4263 Plastic Sheet Method
Concrete must be free from moisture as much as possible (it seldom falls below 15%). Vapor pressures, temperature, humidity,
differentials, and hydrostatic pressures can cause coatings to prematurely fail. The source of moisture, if present, must be
located, and the cause corrected prior to coating.
3. Temperature – Air, surface and material temperatures must be in keeping with requirements for the selected product during
and after coating application, until coating is cured.
4. Contamination – Remove all grease, dirt, paint, oil, laitance, efflorescence, loose mortar, and cement by the
recommendations listed in the surface preparation section.
5. Surface Condition – Hollow areas, bug holes, voids, honeycombs, fin form marks, and all protrusions or rough edges are to
be ground or stoned to provide a continuous surface of suitable texture for proper adhesion of the coating. Imperfections may
require filling, as specified, with a recommended Sherwin-Williams product.
6. Concrete Treatment – Hardeners, sealers, form release agents, curing compounds, and other concrete treatments should be
removed to ensure adequate coating adhesion and performance.
Methods of Surface Preparation on Concrete per SSPC-SP13/NACE 6 or ICRI 03732 Surface Cleaning Methods:
Vacuum cleaning, air blast cleaning, and water cleaning per ASTM D4258.
Used to remove dirt, loose material, and/or dust from concrete.
Detergent water cleaning and steam cleaning per ASTM D4258.
Used to remove oils and grease from concrete. Prior to abrasive cleaning, and after abrasive cleaning, surfaces should be
cleaned by one of the methods described above.
Mechanical Surface Preparation Methods:
Dry abrasive blasting, wet abrasive blasting, vacuum assisted abrasive blasting, and centrifugal shot abrasive blasting per
ASTM D4259. Used to remove contaminants, laitance, and weak concrete, to expose subsurface voids, and to produce a sound
concrete surface with adequate profile and surface porosity.
High-pressure water cleaning or water jetting per SSPC-SP12-NACE5.
Used to remove contaminants, laitance, and weak concrete, to expose subsurface voids, and to produce a sound concrete surface
with adequate profile and surface porosity.
Impact tool methods per ASTM D4259.
Used to remove existing coatings, laitance, and weak concrete. Methods include scarifying, planing, scabbling, and rotary
peening. Impact tools may fracture concrete surfaces or cause microcracking requiring surface repair.
Power tool methods per ASTM D4259.
Used to remove existing coatings, laitance, weak concrete, and protrusions in concrete. Methods include circular grinding,
sanding, and wire brushing. These methods may not produce the required surface profile to ensure adequate adhesion of
subsequent coatings.
Chemical Surface Preparation Methods:
Acid etching per ASTM D4260. Use to remove some surface contaminants, laitance, and weak concrete, and to provide a
surface profile on horizontal concrete surfaces. This method requires complete removal of all reaction products and pH testing
to ensure neutralization of the acid. Not recommended for vertical surfaces. Etching with hydrochloric acid shall not be used
where corrosion of metal in the concrete is likely to occur. Adequate ventilation and safety equipment required.
1. Clean surface per ASTM D4268
2. Wet surface with clean water
3. Etch with 10-15% muriatic acid solution at the rate of 1 gallon per 75 square feet
4. Scrub with stiff brush
5. Allow sufficient time for scrubbing and until bubbling stops
6. If no bubbling occurs, surface is contaminated. Refer to ASTM D4258 or ASTM D4259
7. Rinse surface two or three times. Remove acid/water each time.
8. Surface should a texture similar to medium grit sandpaper.
9. Neutralize surface with a 3% solution of tri-sodium phosphate and flush with clean water.
10. Allow to dry and check for excess moisture.
Cement Composition Siding/Panels – S-W 6: Remove all surface contamination by washing with an appropriate cleaner,
rinse thoroughly and allow to dry. Existing peeled or checked paint should be scraped and sanded to a sound surface. Glossy
surfaces should be sanded dull. Pressure clean, if needed, with a minimum of 2100 psi pressure to remove all dirt, dust, grease,
oil, loose particles, laitance, foreign material, and peeling or defective coatings. Allow the surface to dry thoroughly. If the
surface is new, test it for pH, many times the pH may be 10 or higher.
Composition Board (Hardboard) – S-W 9: Some composition boards may exude a waxy material that must be removed with
a solvent prior to coating. Whether factory primed or unprimed, exterior composition board siding (hardboard) must be cleaned
thoroughly and primed with an alkyd primer.
Copper – S-W 7: Remove all oil, grease, dirt, oxide and other foreign material by cleaning per SSPC-SP2, Hand Tool
Cleaning.
Drywall—Interior and Exterior – S-W 8: Must be clean and dry. All nail heads must be set and spackled. Joints must be
taped and covered with a joint compound. Spackled nail heads and tape joints must be sanded smooth and all dust removed
prior to painting. Exterior surfaces must be spackled with exterior grade compounds.
Galvanized Metal – S-W 10: Allow to weather a minimum of 6 months prior to coating. Clean per SSPC-SP1 using detergent
and water or a degreasing cleaner, then prime as required. When weathering is not possible or the surface has been treated with
chromates or silicates, first Solvent Clean per SSPC-SP1 and apply a test area, priming as required. Allow the coating to dry at
least one week before testing. If adhesion is poor, Brush Blast per SSPC-SP16 is necessary to remove these treatments.
Plaster – S-W 11: Must be allowed to dry thoroughly for at least 30 days before painting. Room must be ventilated while
drying; in cold, damp weather, rooms must be heated. Damaged areas must be repaired with an appropriate patching material.
Bare plaster must be cured and hard. Textured, soft, porous, or powdery plaster should be treated with a solution of 1 pint
household vinegar to 1 gallon of water. Repeat until the surface is hard, rinse with clear water and allow to dry.
Steel/Ferrous Metal Substrates
SSPC-SP1- Solvent Cleaning: Solvent cleaning is a method for removing all visible oil, grease, soil, drawing and cutting
compounds, and other soluble contaminants. Solvent cleaning does not remove rust or mill scale. Change rags and cleaning
solution frequently so that deposits of oil and grease are not spread over additional areas in the cleaning process. Be sure to
allow adequate ventilation. Follow manufacturer's safety recommendations when using solvents. For complete instructions,
refer to Steel Structures Paint Council Surface Preparation Specification No.1. (Refer to each products cleaning instructions.
Many acrylic coatings will state; When cleaning the surface per SSPC-SP1, use only an emulsifying industrial detergent,
followed by a water rinse. Do not use hydrocarbon solvents for cleaning.)
SSPC-SP2 - Hand Tool Cleaning: Hand Tool Cleaning removes all loose mill scale, loose rust, and other detrimental foreign
matter. It is not intended that adherent mill scale, rust, and paint be removed by this process. Mil scale, rust, and paint are
considered adherent if they cannot be removed by lifting with a dull putty knife. Before hand tool cleaning, remove visible oil,
grease, soluble welding residues, and salts by the methods outlined in SSPC-SP1. For complete instructions, refer to Steel
Structures Paint Council Surface Preparation Specification No.2.
SSPC-SP3 - Power Tool Cleaning: Power Tool Cleaning removes all loose mill scale, loose rust, and other detrimental foreign
matter. It is not intended that adherent mill scale, rust, and paint be removed by this process. Mil scale, rust, and paint are
considered adherent if they cannot be removed by lifting with a dull putty knife. Before power tool cleaning, remove visible oil,
grease, soluble welding residues, and salts by the methods outlined in SSPC-SP1. For complete instructions, refer to Steel
Structures Paint Council Surface Preparation Specification No.3.
SSPC-SP5 / NACE 1 - White Metal Blast Cleaning: A White Metal Blast Cleaned surface, when viewed without
magnification, shall be free of all visible oil, grease, dirt, dust, mill scale, rust, paint, oxides, corrosion products, and other
foreign matter. Before blast cleaning, visible deposits of oil or grease shall be removed by any of the methods specified in
SSPC-SP 1 or other agreed upon methods. For complete instructions, refer to Joint Surface Preparation Standard SSPC-SP5/
NACE No.1.
SSPC-SP6 / NACE 3 - Commercial Blast Cleaning: A Commercial Blast Cleaned surface, when viewed without
magnification, shall be free of all visible oil, grease, dirt, dust, mill scale, rust, paint, oxides, corrosion products, and other
foreign matter, except for staining. Staining shall be limited to no more than 33 percent of each square inch of surface area and
may consist of light shadows, slight streaks, or minor discoloration caused by stains of rust, stains of mill scale, or stains of
previously applied paint. Before blast cleaning, visible deposits of oil or grease shall be removed by any of the methods
specified in SSPC-SP 1 or other agreed upon methods. For complete instructions, refer to Joint Surface Preparation Standard
SSPC-SP6/NACE No.3.
SSPC-SP7 / NACE 4 - Brush-Off Blast Cleaning: A Brush-Off Blast Cleaned surface, when viewed without magnification,
shall be free of all visible oil, grease, dirt, dust, loose mill scale, loose rust, and loose paint. Tightly adherent mill scale, rust,
and paint may remain on the surface. Mil scale, rust, and coating are considered adherent if they cannot be removed by lifting
with a dull putty knife. Before blast cleaning, visible deposits of oil or grease shall be removed by any of the methods specified
in SSPC-SP 1 or other agreed upon methods. For complete instructions, refer to Joint Surface Preparation Standard
SSPC-SP7/NACE No.4.
SSPC-SP10 / NACE 2 - Near-White Blast Cleaning: A Near White Blast Cleaned surface, when viewed without
magnification, shall be free of all visible oil, grease, dirt, dust, mill scale, rust, paint, oxides, corrosion products, and other
foreign matter, except for staining. Staining shall be limited to no more than 5 percent of each square inch of surface area and
may consist of light shadows, slight streaks, or minor discoloration caused by stains of rust, stains of mill scale, or stains of
previously applied paint. Before blast cleaning, visible deposits of oil or grease shall be removed by any of the methods
specified in SSPC-SP 1 or other agreed upon methods. For complete instructions, refer to Joint Surface Preparation Standard
SSPCSP10/ NACE No.2.
SSPC-SP11 - Power Tool Cleaning to Bare Metal: Metallic surfaces that are prepared according to this specification, when
viewed without magnification, shall be free of all visible oil, grease, dirt, dust, mill scale, rust, paint, oxide corrosion products,
and other foreign matter. Slight residues of rust and paint may be left in the lower portions of pits if the original surface is
pitted. Prior to power tool surface preparation, remove visible deposits of oil or grease by any of the methods specified in SSPC
-SP 1, Solvent Cleaning, or other agreed upon methods. For complete instructions, refer to Steel Structures Paint Council
Surface Preparation Specification No.11.
SSPC-SP12 / NACE 5 - Surface Preparation and Cleaning of Metals by Waterjetting Prior to Recoating: High- and Ultra
-High Pressure Water Jetting for Steel and Other Hard Materials This standard provides requirements for the use of high- and
ultra-high pressure water jetting to achieve various degrees of surface cleanliness. This standard is limited in scope to the use of
water only, without the addition of solid particles in the stream. For complete instructions, refer to Joint Surface Preparation
Standard SSPC-SP12/NACE No.5.
SSPC-SP13 / NACE 6 or ICRI 03732 - Surface Preparation of Concrete: This standard gives requirements for surface
preparation of concrete by mechanical, chemical, or thermal methods prior to the application of bonded protective coating or
lining systems. The requirements of this standard are applicable to all types of cementitious surfaces including cast-in-place
concrete floors and walls, precast slabs, masonry walls and shotcrete surfaces. An acceptable prepared concrete surface should
be free of contaminants, laitance, loosely adhering concrete, and dust, and should provide a dry, sound, uniform substrate
suitable for the application of protective coating or lining systems. Depending upon the desired finish and system, a block filler
may be required. For complete instructions, refer to Joint Surface Preparation Standard SSPC-SP13/NACE No.6 or ICRI 03732
SSPC-SP14 / NACE 8 – Industrial Blast Cleaning: This standard gives requirements for industrial blast cleaning of
unpainted or painted steel surfaces by the use of abrasives. This joint standard allows defined quantities of mill scale and/or old
coating to remain on the surface. An industrial blast cleaned surface, when viewed without magnification, shall be free of all
visible oil, grease, dust, and dirt. Traces of tightly adherent mill scale, rust, and coating residue are permitted to remain on 10%
of each unit area of the surface. The traces of mill scale, rust, and coating shall be considered tightly adherent if they cannot be
lifted with a dull putty knife. Shadows, streaks, and discolorations caused by stains of rust, stains of mill scale, and stains of
previously applied coating may be present on the remainder of the surface.
SSPC-SP16 Brush-Off Blast Cleaning of Coated and Uncoated Galvanized Steel, Stainless Steels, and Non-Ferrous
Metals: This standard covers the requirements for brush-off blast cleaning of uncoated or coated metal surfaces other than
carbon steel by the use of abrasives. These requirements include visual verification of the end condition of the surface and
materials and procedures necessary to achieve and verify the end condition. A brush-off blast cleaned non-ferrous metal
surface, when viewed without magnification, shall be free of all visible oil, grease, dirt, dust, metal oxides (corrosion products),
and other foreign matter. Intact, tightly adherent coating is permitted to remain. A coating is considered tightly adherent if it
cannot be removed by lifting with a dull putty knife.
High- and Ultra-High Pressure Water Jetting for Steel and Other Hard Materials:
SSPC-SP WJ-1/NACE WJ-1: Clean to Bare Substrate (WJ-1) is intended to be similar to the degree of surface cleanliness of
SSPC-SP 5/NACE 1, except that stains are permitted to remain on the surface. This standard is used when the objective is to
remove every trace of rust and other corrosion products, coating and mill scale.
SSPC-SP WJ-2/NACE WJ-2: Very Thorough Cleaning (WJ-2) is intended to be similar to the degree of surface cleanliness of
SSPC-SP 10/NACE 2, except that tightly adherent material, rather than only stains, is permitted to remain on the surface. This
standard is used when the objective is to remove almost all rust and other corrosion products, coating, and mill scale.
SSPC-SP WJ-3/NACE WJ-3: Thorough Cleaning (WJ-3) is intended to be similar to the degree of surface cleanliness of
SSPC-SP 10/NACE 2, except that tightly adherent material, rather than only stains, is permitted to remain on the surface. This
standard is used when the objective is to remove much of the rust and other corrosion products, coating, and mil scale, leaving
tightly adherent thin films.
SSPC-SP WJ-4/NACE WJ-4: Light Cleaning (WJ-4) is intended to be similar to the degree of surface cleanliness of SSPC-
SP 10/NACE 2, except that tightly adherent material, rather than only stains, is permitted to remain on the surface. This
standard is used when the objective is to allow as much of the tightly adherent rust and other corrosion products, coating, and
mill scale to remain as possible, Discoloration of the surface may be present.
Water Blasting NACE Standard RP-01-72: Removal of oil grease dirt, loose rust, loose mill scale, and loose paint by water
at pressures of 2,000 to 2,500 psi at a flow of 4 to 14 gallons per minute.
Stucco S-W 22 :Must be clean and free of any loose stucco. If recommended procedures for applying stucco are followed, and
normal drying conditions prevail, the surface may be painted in 30 days. The pH of the surface should be between 6 and 9.
Wood—Exterior – S-W 23: Must be clean and dry. Prime and paint as soon as possible. Knots and pitch streaks must be
scraped, sanded, and spot primed before a full priming coat is applied. Patch all nail holes and imperfections with a wood filler
or putty and sand smooth. Caulk should be applied after priming.
Wood—Interior – S-W 24: All finishing lumber and flooring must be stored in dry, warm rooms to prevent absorption of
moisture, shrinkage, and roughening of the wood. All surfaces must be sanded smooth, with the grain, never across it. Surface
blemishes must be corrected and the area cleaned of dust before coating.
Vinyl Siding, Architectural Plastics, PVC & Fiberglass: – S-W 24: Clean the surface thoroughly by scrubbing with warm,
soapy water. Rinse thoroughly, prime with appropriate white primer. Do not paint vinyl with any color darker than the original
color. Do not paint vinyl with a color having a Light Reflective Value (LRV) of less than 56 unless VinylSafe® Colors are used.
If VinylSafe® Colors are not used and darker colors lower than an LRV of 56 are, the vinyl may warp. Follow all painting
guidelines of the vinyl manufacturer when painting. Only paint properly installed vinyl siding. Deviating from the
manufacturer's painting guidelines may cause the warranty to be voided.
Previously Coated Surfaces – S-W 12: Maintenance painting will frequently not permit or require complete removal of all old
coatings prior to repainting. However, all surface contamination such as oil, grease, loose paint, mill scale dirt, foreign matter,
rust, mold, mildew, mortar, efflorescence, and sealers must be removed to assure sound bonding to the tightly adhering old
paint. Glossy surfaces of old paint films must be clean and dull before repainting. Thorough washing with an abrasive cleanser
will clean and dull in one operation, or, wash thoroughly and dull by sanding. Spot prime any bare areas with an appropriate
primer. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of
the system. Check for compatibility by applying a test patch of the recommended coating system, covering at least 2 to 3 square
feet. Allow to dry one week before testing adhesion per ASTM D3359. If the coating system is incompatible, complete removal
is required per ASTM D4259.
Touch-Up, Maintenance and Repair
For a protective coating system to provide maximum long-term protection, regularly scheduled maintenance is required.
Maintenance includes inspection of painted areas, cleaning of surfaces to remove oils, chemicals, and other contaminants, and
touch-up of areas where the coatings have been damaged. Highly corrosive areas, such as those subjected to frequent chemical
spillage, corrosive fumes, and/or high abrasion or temperature areas should be inspected frequently – every six months, for
example. Areas exposed to less severe conditions, such as interiors and exteriors of potable water tanks, may be inspected
annually to assess the condition of the coating system.
The SSPC-VIS 2, Standard Method for Evaluating Degree of Rusting on Painted Steel Surfaces, can be used as a guide to
determine appropriate touch-up and repairs maintenance schedules. Touch-up would be suggested when the surface resembles
Rust Grade 5-S (Spot Rusting), 6-G (General Rusting), or 6-P (Pinpoint Rusting). Surface preparation would generally consist
of SSPC-SP2, SP3, SP11, or SP12. Overcoating a well protected, but aged steel surface showing no evidence of rusting, may be
achieved by Low Pressure Water Cleaning per SSPC-SP12/WJ4, and applying an appropriate coating system.
Full removal of the existing coating system by abrasive blasting would be recommended when the surface resembles Rust
Grade 3-S (Spot Rusting), 4-G (General Rusting), or 4-P (Pinpoint Rusting). When the coating system has deteriorated to
encompass approximately 33% of the surface area, it is always more economical to consider full removal and reapplication of
the appropriate protective coating system.
Mildew –Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area
prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning
solutions may be advised.
Mildew may be removed before painting by washing with a solution of 1 part liquid bleach and 3 parts water. Apply the
solution and scrub the mildewed area. Allow the solution to remain on the surface for 10 minutes. Rinse thoroughly with water
and allow the surface to dry before painting. Wear protective eyewear, waterproof gloves, and protective clothing. Quickly
wash off any of the mixture that comes in contact with your skin. Do not add detergents or ammonia to the bleach/water
solution.
Specification
OXOBOXO LOFTS
Reference Pages
SURFACE PREPARATION
WARNING! Removal of old paint by
sanding, scraping or other means may
generate dust or fumes that contain lead.
Exposure to lead dust or fumes may
cause brain damage or other adverse
health effects, especially in children or
pregnant women. Controlling exposure to
lead or other hazardous substances
requires the use of proper protective
equipment, such as a properly fitted
respirator (NIOSH approved) and proper
containment and cleanup. For more
information, call the National Lead
Information Center at 1-800-424-LEAD
(in US) or contact your local health
authority.
Remove all surface contamination by
washing with an appropriate cleaner,
rinse thoroughly and allow to dry. Existing
peeled or checked paint should be
scraped and sanded to a sound surface.
Glossy surfaces should be sanded dull.
Recognize that any surface preparation
short of total removal of the old coating
may compromise the service length of the
system.
Special recommendations - After
priming stained areas, allow to dry 4
hours, test a small area for bleeding by
applying the topcoat before painting the
entire project. If the stain bleeds through,
apply a second coat of primer and allow
to dry overnight and retest before
topcoating.
Fire restoration work - Thoroughly clean
the surface before applying to smoke
stained areas. Apply one or two coats of
PrepRite ProBlock Latex Primer/Sealer
and test a small area for bleeding before
painting the entire surface.
Testing- Always check for compatibility
and adhesion to the surface by applying a
test patch of 2 - 3 square feet. Allow to
dry thoroughly for 1 week before
checking adhesion.
CHARACTERISTICS
• Assures uniform appearance of
topcoats
• Fast dry
• Apply at temperatures down to 35°F
• Assures adhesion of the topcoat to
slick, glossy surfaces
• Seals out solvent sensitive stains - tar,
solvent based markers, etc.
• Seals minor dried water stains and
tannin
• Provides easy “slip” for positioning of
wallpaper
Use on interior:
• Ceiling Tiles
• Paneling
• Wall Laminate
• Cured Plaster
• Varnished Woodwork
• Kitchen Cabinets
• Ceramic Wall Tile
• Under wallcovering
Use on interior & exterior:
• Wood
• Aluminum
• Galvanized Metal
• Previously Painted Surfaces
• PVC Piping
• Drywall
• Concrete and Masonry
• Many Plastics
• Glossy Surfaces
• Fiberglass
• Copper
• Glazed Block
Anti-microbial - This product contains
agents which inhibit the growth of
microbes on the surface of this paint film.
108.04A
PREPRITE® PROBLOCK®
Interior/Exterior Latex
Primer/Sealer
B51-600 Series As of 02/22/2017, Complies with: OTC Yes LEED® 09 NC CI Yes OTC Phase II Yes LEED® 09 CS Yes SCAQMD Yes LEED® 09 H Yes CARB Yes LEED® v4 Emissions Yes CARB SCM2007 Yes LEED® v4 VOC Yes Canada Yes MPI Yes
2/2017 www.sherwin-williams.com continued on back
CHARACTERISTICS
Color: White & Deep Base
Coverage: 400 sq ft/gal
@ 4 mils wet; 1.4 mils dry
Drying Time, @ 77°F, 50% RH:
Touch: 30 minutes
Recoat as a primer 1 hour
Recoat as a stain sealer: 4 hours
To apply wallcovering 3 hours
Drying and recoat times are temperature, humidity
and film thickness dependent.
Flash Point: N/A
Finish: 5-10 units @ 85°
Tinting with CCE only
Base oz/gal Strength
White 0 - 4 100%
Deep Base 4-12 100%
Vehicle Type: Styrenated Acrylic Latex
B51W00620
VOC (less exempt solvents):
<50 g/L; <0.42 lb/gal
As per 40 CFR 59.406 and SOR/2009-264, s.12
Volume Solids: 35 ± 2%
Weight Solids: 52 ± 2%
Weight per Gallon: 10.9 lb
For best topcoat color development, use
the recommended "P"-shade primer. If
desired, up to 4 oz per gallon of
ColorCast Ecotoners can be used.
Check color before use.
When spot priming on some surfaces, a
non-uniform appearance of the final coat
may result, due to differences in holdout
between primed and unprimed areas. To
avoid this, prime the entire surface rather
than spot priming.
For optimal performance, this primer
must be topcoated with a latex, alkyd/oil,
water based epoxy, or solvent based
epoxy coating on architectural
applications.
For exterior exposure, this primer must
be topcoated within 14 days with
architectural latex or oil finishes.
For better performance when priming an
entire house, use Exterior Latex or Oil-
Based Primers
GREENGUARD
PRODUCT CERTIFIED FOR LOW CHEMICAL EMISSIONS
UL.COM/GG UL 2818
GOLD
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit
www.paintdocs.com to obtain the most current
version of the PDS and/or an SDS.
108.04A
PREPRITE® PROBLOCK®
Interior/Exterior Latex
Primer/Sealer
B51-600 Series
APPLICATION
When the air temperature is at 35°F,
substrates may be colder; prior to
painting, check to be sure the air,
surface, and material temperature are
above 35°F and at least 5°F above the
dew point. Avoid using if rain or snow is
expected within 2-3 hours. Air and
surface temperatures must not drop
below 35°F for 48 hours after application.
Do not reduce for stain blocking.
No reduction necessary.
Brush - Use a nylon/polyester brush.
Roller - Use a 3/8” nap soft woven roller
cover.
Spray—Airless
Pressure ................................ 2000 psi
Tip ...................................... .015"-.021"
Tips-General Priming: PrepRite ProBlock
Latex Primer/Sealer can be topcoated in
1 hour in non-stain blocking applications.
On hard, slick, glossy, or otherwise hard
to paint surfaces, after preparing the
surface, apply a test area of this primer,
allow to dry properly and test for
adhesion.
When used as a primer under
wallcovering. After wallcovering has
been applied and the adhesive has dried
and cured, wait at least 21 days before
removing the wallcovering to avoid
damage to the drywall.
CLEANUP INFORMATION
Clean spills, spatters, hands and tools
immediately after use with soap and
warm water. After cleaning, flush spray
equipment with a compliant cleanup
solvent to prevent rusting of the
equipment. Follow manufacturer’s safety
recommendations when using solvents.
CAUTIONS
Protect from freezing..
Before using, carefully read CAUTIONS
on label.
HOTW 02/22/2017 B51W00620 18 00 KOR, SP
SURFACE PREPARATION
Plaster - Must be cured, usually 30 days,
and hard. If painting cannot wait, allow
the surface to dry 7 days and prime with
Loxon Concrete and Masonry Primer.
Soft, porous, or powdery plaster should
be treated with a solution of 1 pint
household vinegar to 1 gallon of water.
Repeat until the surface is hard, rinse
with water and allow to dry before
painting.
Wood - Sand any exposed wood to a
fresh surface. Patch all holes and
imperfections with a wood filler or putty
and sand smooth.
Tile, laminate, ceramic and plastic tiles,
and similar glossy surfaces, must be free
of all oil, grease, and soap residue. Do
not use this product in areas subject to
excessive water, e.g.: in showers, around
sinks, on counter tops.
Caulking - Fill gaps between walls,
ceilings, crown moldings, and other trim
with the appropriate caulk after priming
the surface.
Mildew - Prior to attempting to remove
mildew, it is always recommended to test
any cleaner on a small, inconspicuous
area prior to use. Bleach and bleaching
type cleaners may damage or discolor
existing paint films. Bleach alternative
cleaning solutions may be advised.
Mildew may be removed before painting
by washing with a solution of 1 part liquid
bleach and 3 parts water. Apply the
solution and scrub the mildewed area.
Allow the solution to remain on the
surface for 10 minutes. Rinse thoroughly
with water and allow the surface to dry
before painting. Wear protective eyewear,
waterproof gloves, and protective
clothing. Quickly wash off any of the
mixture that comes in contact with your
skin. Do not add detergents or ammonia
to the bleach/water solution.
page 1 of 4
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
24 00 [2809]
Date of Preparation
Nov 25, 2019
PRODUCT NUMBER
B51W620
PRODUCT NAME
PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer, White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B51W620 = | Acute | Chronic |
Product Weight
10.89 lb/gal
Specific Gravity
1.31
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 48 63
Volatile Organic Compounds - U.S. EPA / Canada
B51W620
LB/Gal g/L
Coating Density 10.89 1304
By wt By vol
Total Volatiles 48.5%63.5%
Federally exempt solvents
Water 48.4%64.9%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 51.5%36.5%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
B51W620
page 2 of 4
Volatile Organic Compounds - California
B51W620
LB/Gal g/L
Coating Density 10.89 1304
By wt By vol
Total Volatiles 48.5%63.5%
Exempt solvents
Water 48.4%64.9%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 51.5%36.5%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B51W620
LB/Gal g/L
Coating Density 10.89 1304
By wt By vol
Total Volatiles 48.5%63.5%
Exempt solvents
Water 48.4%64.9%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 51.5%36.5%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B51W620
By wt By vol
Total Volatiles 48.5%63.5%
VOC Content LB/Gal g/L
Total 0.00 0
B51W620
page 3 of 4
Volatile Organic Compounds - EU Directive 2010/75/EU
B51W620
By wt By vol
Total Volatiles 48.5%63.5%
VOC Content LB/Gal g/L
Total 0.00 0
Volatile Organic Compounds - Mexico
B51W620
LB/Gal g/L
Coating Density 10.89 1304
By wt By vol
Total Volatiles 48.5%63.5%
Exempt solvents
Water 48.4%64.9%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 51.5%36.5%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B51W620
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
7.19 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
B51W620
page 4 of 4
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B51W620
B51W620Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.
Causes damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
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Section 2. Hazards identification
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. Adequate ventilation required when
sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an
approved particulate respirator (NIOSH approved). Follow respirator manufacturer's
directions for respirator use. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica
which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Talc ≤10 14807-96-6
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
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White
SHW-85-NA-GHS-US
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Date of issue/Date of revision :11/27/2019 Date of previous issue :10/7/2019 Version :18 4/12
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Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Talc 14807-96-6 NIOSH REL (United States, 10/2016).
TWA: 2 mg/m³ 10 hours. Form: Respirable
fraction
ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
talc (none asbestiform)14807-96-6 CA British Columbia Provincial (Canada,
5/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
TWA: 0.1 f/cc 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 3 mg/m³ 8 hours. Form: Respirable
dust.
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction.
TWA: 2 f/cc 8 hours.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form:
Respirable particulate
CA Saskatchewan Provincial (Canada,
7/2013).
TWA: 2 mg/m³ 8 hours. Form: respirable
fraction
Ingredient name Exposure limits
Occupational exposure limits (Canada)
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Environmental exposure
controls
:
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: >94°C (>201.2°F)
8.8
Not available.Odor threshold
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.31
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
Decomposition temperature :Not available.
Heat of combustion :0.514 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Talc Skin - Mild irritant Human -72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
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Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Talc Category 1 Inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Titanium Dioxide -2B -
Talc -3 -
Product/ingredient name NTPIARCOSHA
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Date of issue/Date of revision :11/27/2019 Date of previous issue :10/7/2019 Version :18 8/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
Section 11. Toxicological information
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Date of issue/Date of revision :11/27/2019 Date of previous issue :10/7/2019 Version :18 9/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
International regulations
International lists :
Date of issue/Date of revision :11/27/2019 Date of previous issue :10/7/2019 Version :18 10/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
Section 15. Regulatory information
Vietnam inventory: Not determined.
Section 16. Other information
11/27/2019
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
11/27/2019
10/7/2019
18
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category
1
Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :11/27/2019 Date of previous issue :10/7/2019 Version :18 11/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
Section 16. Other information
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of issue/Date of revision :11/27/2019 Date of previous issue :10/7/2019 Version :18 12/12
B51W620 PrepRite® ProBlock® Interior/Exterior Latex Primer/Sealer
White
SHW-85-NA-GHS-US
101.81A
ProMar® 200 Zero V.O.C.
Interior Latex Flat
B30-2600 Series
CHARACTERISTICS
ProMar 200 Zero V.O.C. Interior Latex Flat is a durable, professional quality, interior vinyl acrylic finish for use on walls and ceilings of primed plaster, wallboard, wood, masonry, and primed metal.
Color:Most Colors
To optimize hide and color development, always use the recommended P-Shade primer
Coverage:350-400 sq. ft. per gallon
@ 4 mils wet;
1.4 mils dry
Drying Time, @ 77°F, 50% RH:
Touch:1 Hour
Recoat:4 Hours
Drying and recoat times are temperature, humidity, and film thickness dependent
Finish:1.5-3.5 units @ 85°
Tinting with CCE only:
Base:oz/gal:Strength:
High Ref White 0-6 SherColor
Extra White 0-7 SherColor
Deep Base 4-12 SherColor
Ultradeep Base 10-12 SherColor
Real Red 0-12 SherColor
Bright Yellow 0-12 SherColorDover White do not tint
Extra White B30W12651
(may vary by color)
V.O.C. (less exempt solvents):
less than 50 grams per litre; 0.42 lbs. per gallonAs per 40 CFR 59.406
Volume Solids:34 ± 2%
Weight Solids:52 ± 2%
Weight per Gallon:11.45 lbs
Flash Point:N/A
Vehicle Type:Vinyl Acrylic
Shelf Life:36 months unopened
Anti-microbial
This product contains agents which inhibit
the growth of mold and mildew on the surface
of this paint film.
COMPLIANCE
As of 09/04/2019, Complies with:
OTC Yes
OTC Phase II Yes
SCAQMD Yes
CARB Yes
CARB SCM 2007 Yes
Canada Yes
LEED® v4 & v4.1 Emissions Yes
LEED® v4 & v4.1 V.O.C.Yes
EPD-NSF® Certified Yes
MIR-Product Lens Certified Yes
MPI®Yes
APPLICATION
Apply at temperatures above 50°F. No reduction needed.
Brush:
Use a nylon/polyester brush.
Roller:
Use a 3/8 to 3/4 inch nap synthetic cover.
Spray—Airless
Pressure 2000 p.s.i.
Tip .017-.021 inch
APPLICATION TIPS
Make sure product is completely agitated (mechanically or manually) before use.
Priming and application of two coats at the recommended film thickness can help where hiding of a previous coating or application to new drywall is a factor.
Using the same method of application and batch to touch up with as that originally used will help improve touch up.
When original application was by spray, preconditioning of touch up paint by running it through the spray tip will help touch up appearance.
SPECIFICATIONS
Block:
1 coat ConFlex Block Filler*
2 coats ProMar 200 Zero V.O.C. Interior Latex
Drywall:
1 coat ProMar 200 Zero V.O.C. Latex Primer
2 coats ProMar 200 Zero V.O.C. Interior Latex
Masonry:
1 coat Loxon Concrete & Masonry Primer*2 coats ProMar 200 Zero V.O.C. Interior Latex
Plaster:
1 coat Loxon Concrete & Masonry Primer*
2 coats ProMar 200 Zero V.O.C. Interior Latex
Wood:
1 coat Premium Wall & Wood Primer*
2 coats ProMar 200 Zero V.O.C. Interior Latex
*These primers contain less than 50 grams per litre V.O.C.
Other primers may be appropriate.
When repainting involves a drastic color
change, a coat of primer will improve the
hiding performance of the topcoat color.
09/2019 www.sherwin-williams.com continued on back
ProMar® 200 Zero V.O.C.
Interior Latex Flat
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority.
Remove all surface contamination by washing
with an appropriate cleaner, rinse thoroughly
and allow to dry. Existing peeled or checked
paint should be scraped and sanded to a
sound surface. Glossy surfaces should be
sanded dull. Stains from water, smoke, ink,
pencil, grease, etc. should be sealed with the
appropriate primer/sealer. Recognize that any
surface preparation short of total removal of the
old coating may compromise the service length
of the system.
Caulking:
Gaps between walls, ceilings, crown moldings, and other interior trim can be filled with the appropriate caulk after priming the surface.
Drywall:
Fill cracks and holes with patching paste/spackle and sand smooth. Joint compounds must be cured and sanded smooth. Remove all sanding dust.
Masonry, Concrete, Cement, Block:
All new surfaces must be cured according to the supplier’s recommendations—usually about 30 days. Remove all form release and curing agents. Rough surfaces can be filled to provide a smooth surface. If painting cannot wait 30 days, allow the surface to cure 7 days and prime the surface with Loxon Concrete & Masonry Primer.
SURFACE PREPARATION
Mildew:
Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised. Mildew may be removed before painting by washing with a solution of 1 part liquid bleach and 3 parts water. Apply the solution and scrub the mildewed area. Allow the solution to remain on the surface for 10 minutes. Rinse thoroughly with water and allow the surface to dry before painting. Wear protective eyewear, waterproof gloves, and protective clothing. Quickly wash off any of the mixture that comes in contact with your skin. Do not add detergents or ammonia to the bleach/water solution.
Plaster:
Bare plaster must be cured and hard. Textured,
soft, porous, or powdery plaster should be
treated with a solution of 1 pint household
vinegar to 1 gallon of water. Repeat until the
surface is hard, rinse with clear water and allow
to dry.
Wood:
Sand any exposed wood to a fresh surface.
Patch all holes and imperfections with a wood
filler or putty and sand smooth.
CAUTIONS
For interior use only. Protect from freezing. Non-photochemically reactive.
Before using, carefully read CAUTIONS
on label
CRYSTALLINE SILICA Use only with adequate ventilation. To avoid overexposure, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air, or wear respiratory protection (NIOSH approved) or leave the area. Adequate ventilation required when sanding or abrading the dried film. If adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer’s directions for respirator use. Avoid contact with eyes and skin. Wash hands after using. Keep container closed when not in use. Do not transfer contents to other containers for storage. FIRST AID: In case of eye contact, flush thoroughly with large amounts of water. Get medical attention if irritation persists. If swallowed, call Poison Control Center, hospital emergency room, or physician immediately. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release crystalline silica which has been shown to cause lung damage and cancer under long term exposure. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
HOTW 09/04/2019 B30W02653 26 00FRC,SP
CLEANUP INFORMATION
Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents.
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams
Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
page 1 of 3
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
13 00 [2969]
Date of Preparation
Oct 23, 2019
PRODUCT NUMBER
B30W12651
PRODUCT NAME
PROMAR® 200 Zero VOC Interior Latex Flat, Extra White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B30W12651 = | Acute | Chronic |
Product Weight
11.45 lb/gal
Specific Gravity
1.38
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 48 66
Volatile Organic Compounds - U.S. EPA / Canada
B30W12651
LB/Gal g/L
Coating Density 11.45 1371
By wt By vol
Total Volatiles 47.6%65.6%
Federally exempt solvents
Water 47.6%65.6%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 52.4%34.4%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
B30W12651
page 2 of 3
Volatile Organic Compounds - California
B30W12651
LB/Gal g/L
Coating Density 11.45 1371
By wt By vol
Total Volatiles 47.6%65.6%
Exempt solvents
Water 47.6%65.6%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 52.4%34.4%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B30W12651
LB/Gal g/L
Coating Density 11.45 1371
By wt By vol
Total Volatiles 47.6%65.6%
Exempt solvents
Water 47.6%65.6%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 52.4%34.4%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B30W12651
By wt By vol
Total Volatiles 48.0%66.1%
VOC Content LB/Gal g/L
Total 0.04 5
Volatile Organic Compounds - EU Directive 2010/75/EU
B30W12651
By wt By vol
Total Volatiles 47.6%65.6%
VOC Content LB/Gal g/L
Total 0.00 0
B30W12651
page 3 of 3
Volatile Organic Compounds - Mexico
B30W12651
LB/Gal g/L
Coating Density 11.45 1371
By wt By vol
Total Volatiles 47.6%65.6%
Exempt solvents
Water 47.6%65.6%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 52.4%34.4%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B30W12651
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
7.63 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PROMAR® 200 Zero VOC Interior Latex Flat
Extra White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B30W12651
B30W12651Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity:
3.1%
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
3.1%
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 3.1%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.
Causes damage to organs through prolonged or repeated exposure. (lungs)
:Hazard statements
Date of issue/Date of revision :2/10/2020 Date of previous issue :11/27/2019 Version :16 1/12
B30W12651 PROMAR® 200 Zero VOC Interior Latex Flat
Extra White
SHW-85-NA-GHS-US
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Kaolin ≤5 1332-58-7
Amorphous Silica ≤3 7631-86-9
Aluminum Hydroxide ≤3 21645-51-2
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision :2/10/2020 Date of previous issue :11/27/2019 Version :16 2/12
B30W12651 PROMAR® 200 Zero VOC Interior Latex Flat
Extra White
SHW-85-NA-GHS-US
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Date of issue/Date of revision :2/10/2020 Date of previous issue :11/27/2019 Version :16 3/12
B30W12651 PROMAR® 200 Zero VOC Interior Latex Flat
Extra White
SHW-85-NA-GHS-US
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
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Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Kaolin 1332-58-7 ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
Amorphous Silica 7631-86-9 NIOSH REL (United States, 10/2016).
TWA: 6 mg/m³ 10 hours.
Aluminum Hydroxide 21645-51-2 ACGIH TLV (United States, 3/2019).
TWA: 1 mg/m³ 8 hours. Form: Respirable
fraction
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Kaolin 1332-58-7 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form:
Respirable
CA British Columbia Provincial (Canada,
5/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: Respirable
dust.
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction.
CA Saskatchewan Provincial (Canada,
7/2013).
Ingredient name Exposure limits
Occupational exposure limits (Canada)
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
STEL: 4 mg/m³ 15 minutes. Form: respirable
fraction
TWA: 2 mg/m³ 8 hours. Form: respirable
fraction
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
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Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.37
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
White.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9.6
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :1.027 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Amorphous Silica Eyes - Mild irritant Rabbit -24 hours 25
mg
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Kaolin Category 1 Inhalation lungs
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Amorphous Silica -3 -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact :No specific data.
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
Causes damage to organs through prolonged or repeated exposure.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
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Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
2/10/2020
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
2/10/2020
11/27/2019
16
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category
1
Calculation method
Procedure used to derive the classification
Classification Justification
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Key to abbreviations :
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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B30W12651 PROMAR® 200 Zero VOC Interior Latex Flat
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SHW-85-NA-GHS-US
108.24
PROMAR® 200
Zero VOC
Interior Latex
Primer
B28W02600
CHARACTERISTICS
Color: White
Coverage: 350 - 400 sq ft/gal
@ 4 mils wet; 1.0 mils dry
Drying Time, @ 77°F, 50% RH:
Touch: 1 hour
Recoat: 4 hours
Drying and recoat times are temperature, humidity
and film thickness dependent.
Flash Point: N/A
Finish: 0 - 5 units @ 85°
Vehicle Type: Vinyl Acrylic
B28W02600
VOC (less exempt solvents):
<50 g/L; <0.42 lb/gal
As per 40 CFR 59.406 and SOR/2009-264, s.12 Volume Solids: 26 ± 2%
Weight Solids: 43 ± 2%
Weight per Gallon: 10.77 lb
WVP Perms (US) 25.8
grains/(hr ft2 in Hg)
Tinting
Requires ColorCast Ecotoners for tinting.
For best topcoat color development, use
the recommended "P"-shade primer. If
desired, up to 4 oz per gallon of
ColorCast Ecotoners can be used to
approximate the topcoat color. Check
color before use.
When spot priming on some surfaces, a
non-uniform appearance of the final coat
may result, due to differences in holdout
between primed and unprimed areas. To
avoid this, prime the entire surface rather
than spot priming.
For optimal performance, this primer
must be topcoated with a latex, alkyd/oil,
water based epoxy, or solvent based
epoxy coating on architectural
applications.
SURFACE PREPARATION
WARNING! Removal of old paint by
sanding, scraping or other means may
generate dust or fumes that contain lead.
Exposure to lead dust or fumes may
cause brain damage or other adverse
health effects, especially in children or
pregnant women. Controlling exposure to
lead or other hazardous substances
requires the use of proper protective
equipment, such as a properly fitted
respirator (NIOSH approved) and proper
containment and cleanup. For more
information, call the National Lead
Information Center at 1-800-424-LEAD
(in US) or contact your local health
authority.
Remove all surface contamination by
washing with an appropriate cleaner,
rinse thoroughly and allow to dry. Existing
peeled or checked paint should be
scraped and sanded to a sound surface.
Glossy surfaces should be sanded dull.
Stains from water, smoke, ink, pencil,
grease, etc. should be sealed with the
appropriate primer/sealer. Recognize that
any surface preparation short of total
removal of the old coating may
compromise the service length of the
system.
Caulking
Fill gaps between walls, ceilings, crown
moldings, and other trim with the
appropriate caulk after priming the
surface.
Drywall
Fill cracks and holes with patching paste/
spackle and sand smooth. Joint
compounds must be cured and sanded
smooth. Remove all sanding dust.
DESCRIPTION
ProMar 200 Zero VOC Interior Latex
Primer is a durable, professional quality,
interior vinyl acrylic primer.
This primer has been designed for use
with the ProMar Series Interior Latex
topcoats providing a complete system.
For use on these interior surfaces:
• Wood
• Drywall
• Plaster
• Masonry
• Primed Metal
• Previously painted surfaces
5/2016 www.sherwin-williams.com continued on back
As of 05/17/2016, Complies with: OTC Yes LEED® 09 NC CI Yes SCAQMD Yes LEED® 09 CS Yes CARB Yes LEED® 09 H & S Yes CARB SCM 2007 Yes LEED® v4 Emissions Yes
MPI Yes LEED® v4 VOC Yes
GREENGUARD
PRODUCT CERTIFIED FOR LOW CHEMICAL EMISSIONS
UL.COM/GG UL 2818
GOLD
The information and recommendations set forth in
this Product Data Sheet are based upon tests con-
ducted by or on behalf of The Sherwin-Williams Com-
pany. Such information and recommendations set
forth herein are subject to change and pertain to the
product offered at the time of publication. Consult
your Sherwin-Williams representative or visit
www.paintdocs.com to obtain the most current ver-
sion of the PDS and/or an SDS.
108.24
PROMAR® 200
Zero VOC
Interior Latex
Primer
B28W02600
APPLICATION
Use at temperatures above 50°F.
No reduction necessary.
Brush
Use a nylon/polyester brush.
Roller
Use a synthetic nap cover
Spray - Airless
Pressure ................................ 2000 psi
Tip ...................................... .017"-.021"
CLEANUP INFORMATION
Clean spills, spatters, hands and tools
immediately after use with soap and warm
water. After cleaning, flush spray equipment
with a compliant cleanup solvent to prevent
rusting of the equipment. Follow
manufacturer’s safety recommendations
when using solvents.
CAUTIONS
For interior use only.
Protect from freezing.
Non-photochemically reactive.
Not for use under wallpaper.
Before using, carefully read CAUTIONS
on label.
HOTW 05/17/2016 B28W02600 21 00
KOR, FRC, SP
SURFACE PREPARATION
Masonry, Concrete, Cement, Block
All new surfaces must be cured according
to the supplier’s recommendations—
usually about 30 days. Remove all form
release and curing agents. Rough
surfaces can be filled to provide a smooth
surface. If painting cannot wait 30 days,
allow the surface to cure 7 days and
prime the surface with Loxon Concrete &
Masonry Primer.
Mildew
Prior to attempting to remove mildew, it is
always recommended to test any cleaner on
a small, inconspicuous area prior to use.
Bleach and bleaching type cleaners may
damage or discolor existing paint films.
Bleach alternative cleaning solutions may
be advised.
Mildew may be removed before painting by
washing with a solution of 1 part liquid
bleach and 3 parts water. Apply the solution
and scrub the mildewed area. Allow the
solution to remain on the surface for 10
minutes. Rinse thoroughly with water and
allow the surface to dry before painting.
Wear protective eyewear, waterproof
gloves, and protective clothing. Quickly
wash off any of the mixture that comes in
contact with your skin. Do not add
detergents or ammonia to the bleach/water
solution.
Plaster
Bare plaster must be cured and hard.
Textured, soft, porous, or powdery plaster
should be treated with a solution of 1 pint
household vinegar to 1 gallon of water.
Repeat until the surface is hard, rinse
with clear water and allow to dry.
page 1 of 3
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
27 00 [2969]
Date of Preparation
Nov 25, 2019
PRODUCT NUMBER
B28W2600
PRODUCT NAME
PROMAR® 200 Zero VOC Interior Latex Primer, White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B28W2600 = | Acute | Chronic |
Product Weight
10.77 lb/gal
Specific Gravity
1.30
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 57 74
Volatile Organic Compounds - U.S. EPA / Canada
B28W2600
LB/Gal g/L
Coating Density 10.77 1290
By wt By vol
Total Volatiles 57.0%73.8%
Federally exempt solvents
Water 57.0%73.8%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 43.0%26.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
B28W2600
page 2 of 3
Volatile Organic Compounds - California
B28W2600
LB/Gal g/L
Coating Density 10.77 1290
By wt By vol
Total Volatiles 57.0%73.8%
Exempt solvents
Water 57.0%73.8%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 43.0%26.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B28W2600
LB/Gal g/L
Coating Density 10.77 1290
By wt By vol
Total Volatiles 57.0%73.8%
Exempt solvents
Water 57.0%73.8%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 43.0%26.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B28W2600
By wt By vol
Total Volatiles 57.0%73.8%
VOC Content LB/Gal g/L
Total 0.00 0
Volatile Organic Compounds - EU Directive 2010/75/EU
B28W2600
By wt By vol
Total Volatiles 57.0%73.8%
VOC Content LB/Gal g/L
Total 0.00 0
B28W2600
page 3 of 3
Volatile Organic Compounds - Mexico
B28W2600
LB/Gal g/L
Coating Density 10.77 1290
By wt By vol
Total Volatiles 57.0%73.8%
Exempt solvents
Water 57.0%73.8%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 43.0%26.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B28W2600
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
14.92 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PROMAR® 200 Zero VOC Interior Latex Primer
White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B28W2600
B28W2600Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
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Section 2. Hazards identification
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. Adequate ventilation required when
sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an
approved particulate respirator (NIOSH approved). Follow respirator manufacturer's
directions for respirator use. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica
which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Calcium Carbonate <10 1317-65-3
Titanium Dioxide ≤10 13463-67-7
Amorphous Silica ≤3 7631-86-9
Heavy Paraffinic Oil ≤1 64742-65-0
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
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Section 4. First aid measures
such as a collar, tie, belt or waistband.
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
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Calcium Carbonate 1317-65-3 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Amorphous Silica 7631-86-9 NIOSH REL (United States, 10/2016).
TWA: 6 mg/m³ 10 hours.
Heavy Paraffinic Oil 64742-65-0 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2019).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Control parameters
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Liquid.
Not available.
1.29
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Flash point Closed cup: >94°C (>201.2°F)
9
Not available.Odor threshold
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
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Section 9. Physical and chemical properties
Solubility Not available.
Auto-ignition temperature Not available.
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
Decomposition temperature :Not available.
Heat of combustion :0.928 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Amorphous Silica Eyes - Mild irritant Rabbit -24 hours 25
mg
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
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Section 11. Toxicological information
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable.Respiratory tract
irritation
Name Category
Not available.
Aspiration hazard
Name Result
Heavy Paraffinic Oil ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Titanium Dioxide -2B -
Amorphous Silica -3 -
Product/ingredient name NTPIARCOSHA
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
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Section 11. Toxicological information
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
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Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
International regulations
International lists :
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Section 15. Regulatory information
Vietnam inventory: Not determined.
Section 16. Other information
11/27/2019
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
11/27/2019
10/23/2019
16
Hazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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Section 16. Other information
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
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SHW-85-NA-GHS-US
101.83A
ProMar® 200 Zero V.O.C.
Interior Latex Eg-Shel
B20-2600 Series
CHARACTERISTICS
ProMar 200 Zero V.O.C. Interior Latex Eg-Shel is a durable, professional quality, interior vinyl acrylic finish for use on walls, ceilings, and trim of primed plaster, wallboard, wood, masonry, and primed metal.
Color:Most Colors
To optimize hide and color development, always use the recommended P-Shade primer
Coverage:350 - 400 sq. ft. per gallon
@ 4 mils wet;
1.7 mils dry
Drying Time, @ 77°F, 50% RH:
Touch:1 Hour
Recoat:4 Hours
Drying and recoat times are temperature, humidity, and film thickness dependent
Finish:15-20 units @ 85°
5+ units @60°
Tinting with CCE only:
Base:oz/gal:Strength:
High Ref White 0-6 SherColor
Extra White 0-7 SherColor
Deep Base 4-12 SherColor
Ultradeep Base 10-12 SherColorReal Red 0-12 SherColor
Bright Yellow 0-12 SherColor
Dover White do not tint
Extra White B20W12651
(may vary by color)
V.O.C. (less exempt solvents):
less than 50 grams per litre; 0.42 lbs. per gallonAs per 40 CFR 59.406
Volume Solids:42 ± 2%
Weight Solids:54 ± 2%
Weight per Gallon:11.82 lbs
Flash Point:N/A
Vehicle Type:Vinyl Acrylic
Shelf Life:36 months unopened
Anti-microbialThis product contains agents which inhibit the growth of mold and mildew on the surface of this paint film.
COMPLIANCE
As of 09/04/2019, Complies with:
OTC Yes
OTC Phase II Yes
SCAQMD Yes
CARB Yes
CARB SCM 2007 Yes
Canada Yes
LEED® v4 & v4.1 Emissions Yes
LEED® v4 & v4.1 V.O.C.Yes
EPD-NSF® Certified Yes
MIR-Product Lens Certified Yes
MPI®Yes
APPLICATION
Apply at temperatures above 50°F.
No reduction needed.
Brush:
Use a nylon/polyester brush.
Roller:
Use a 3/8 to 3/4 inch nap synthetic cover.
Spray—Airless
Pressure 2000 p.s.i.
Tip .017-.021 inch
APPLICATION TIPS
Make sure product is completely agitated
(mechanically or manually) before use.
Priming and application of two coats at the recommended film thickness can help where hiding of a previous coating or application to new drywall is a factor.
Using the same method of application and
batch to touch up with as that originally used
will help improve touch up.
When original application was by spray, preconditioning of touch up paint by running it through the spray tip will help touch up appearance.
SPECIFICATIONS
Block:
1 coat ConFlex Block Filler*
2 coats ProMar 200 Zero V.O.C. Interior Latex
Drywall:
1 coat ProMar 200 Zero V.O.C. Latex Primer
2 coats ProMar 200 Zero V.O.C. Interior Latex
Masonry:
1 coat Loxon Concrete & Masonry Primer*2 coats ProMar 200 Zero V.O.C. Interior Latex
Plaster:
1 coat Loxon Concrete & Masonry Primer*
2 coats ProMar 200 Zero V.O.C. Interior Latex
Wood:
1 coat Premium Wall & Wood Primer*
2 coats ProMar 200 Zero V.O.C. Interior Latex
*These primers contain less than 50 grams per litre V.O.C.
Other primers may be appropriate.
When repainting involves a drastic color change, a coat of primer will improve the hiding performance of the topcoat color.
09/2019 www.sherwin-williams.com continued on back
ProMar® 200 Zero V.O.C.
Interior Latex Eg-Shel
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority.
Remove all surface contamination by washing
with an appropriate cleaner, rinse thoroughly
and allow to dry. Existing peeled or checked
paint should be scraped and sanded to a
sound surface. Glossy surfaces should be
sanded dull. Stains from water, smoke, ink,
pencil, grease, etc. should be sealed with the
appropriate primer/sealer. Recognize that any
surface preparation short of total removal of the
old coating may compromise the service length
of the system.
Caulking:
Gaps between walls, ceilings, crown moldings, and other interior trim can be filled with the appropriate caulk after priming the surface.
Drywall:
Fill cracks and holes with patching paste/spackle and sand smooth. Joint compounds must be cured and sanded smooth. Remove all sanding dust.
Masonry, Concrete, Cement, Block:
All new surfaces must be cured according to the supplier’s recommendations—usually about 30 days. Remove all form release and curing agents. Rough surfaces can be filled to provide a smooth surface. If painting cannot wait 30 days, allow the surface to cure 7 days and prime the surface with Loxon Concrete & Masonry Primer.
SURFACE PREPARATION
Mildew:
Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised.
Mildew may be removed before painting by
washing with a solution of 1 part liquid bleach
and 3 parts water. Apply the solution and scrub
the mildewed area. Allow the solution to remain
on the surface for 10 minutes. Rinse thoroughly
with water and allow the surface to dry before
painting. Wear protective eyewear, waterproof
gloves, and protective clothing. Quickly wash
off any of the mixture that comes in contact with
your skin. Do not add detergents or ammonia
to the bleach/water solution.
Plaster:
Bare plaster must be cured and hard. Textured, soft, porous, or powdery plaster should be treated with a solution of 1 pint household vinegar to 1 gallon of water. Repeat until the surface is hard, rinse with clear water and allow to dry.
Wood:
Sand any exposed wood to a fresh surface. Patch all holes and imperfections with a wood filler or putty and sand smooth.
CAUTIONS
For interior use only. Protect from freezing. Non-photochemically reactive.
Before using, carefully read CAUTIONS
on label
CRYSTALLINE SILICA Use only with adequate ventilation. To avoid overexposure, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air, or wear respiratory protection (NIOSH approved) or leave the area. Adequate ventilation required when sanding or abrading the dried film. If adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer’s directions for respirator use. Avoid contact with eyes and skin. Wash hands after using. Keep container closed when not in use. Do not transfer contents to other containers for storage. FIRST AID: In case of eye contact, flush thoroughly with large amounts of water. Get medical attention if irritation persists. If swallowed, call Poison Control Center, hospital emergency room, or physician immediately. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release crystalline silica which has been shown to cause lung damage and cancer under long term exposure. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
HOTW 09/04/2019 B20T02654 30 00FRC,SP
CLEANUP INFORMATION
Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents.
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams
Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
page 1 of 3
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
18 00 [3029]
Date of Preparation
Nov 26, 2019
PRODUCT NUMBER
B20W12651
PRODUCT NAME
PROMAR® 200 Zero VOC Interior Latex Eg-Shel, Extra White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Ave.
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B20W12651 = | Chronic |
Product Weight
10.82 lb/gal
Specific Gravity
1.30
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 46 58
Volatile Organic Compounds - U.S. EPA / Canada
B20W12651
LB/Gal g/L
Coating Density 10.82 1296
By wt By vol
Total Volatiles 45.7%57.9%
Federally exempt solvents
Water 45.7%57.9%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 54.3%42.1%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
B20W12651
page 2 of 3
Volatile Organic Compounds - California
B20W12651
LB/Gal g/L
Coating Density 10.82 1296
By wt By vol
Total Volatiles 45.7%57.9%
Exempt solvents
Water 45.7%57.9%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 54.3%42.1%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B20W12651
LB/Gal g/L
Coating Density 10.82 1296
By wt By vol
Total Volatiles 45.7%57.9%
Exempt solvents
Water 45.7%57.9%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 54.3%42.1%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B20W12651
By wt By vol
Total Volatiles 46.0%58.2%
VOC Content LB/Gal g/L
Total 0.02 3
Volatile Organic Compounds - EU Directive 2010/75/EU
B20W12651
By wt By vol
Total Volatiles 45.7%57.9%
VOC Content LB/Gal g/L
Total 0.00 0
B20W12651
page 3 of 3
Volatile Organic Compounds - Mexico
B20W12651
LB/Gal g/L
Coating Density 10.82 1296
By wt By vol
Total Volatiles 45.7%57.9%
Exempt solvents
Water 45.7%57.9%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 54.3%42.1%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B20W12651
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
10.82 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :Manufactured by:
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B20W12651
B20W12651Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
Date of issue/Date of revision :11/28/2019 Date of previous issue :10/29/2019 Version :13 1/11
B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 2. Hazards identification
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Potential acute health effects
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B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 6. Accidental release measures
Environmental precautions
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
CAS #
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Extra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Ingredient name Exposure limits
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
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B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.3
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
White.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9.6
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :0.7 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Date of issue/Date of revision :11/28/2019 Date of previous issue :10/29/2019 Version :13 7/11
B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Date of issue/Date of revision :11/28/2019 Date of previous issue :10/29/2019 Version :13 8/11
B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision :11/28/2019 Date of previous issue :10/29/2019 Version :13 9/11
B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
11/28/2019
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Key to abbreviations :
11/28/2019
10/29/2019
13
Hazardous Material Information System (U.S.A.)
0
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
Date of issue/Date of revision :11/28/2019 Date of previous issue :10/29/2019 Version :13 10/11
B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Notice to reader
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :11/28/2019 Date of previous issue :10/29/2019 Version :13 11/11
B20W12651 PROMAR® 200 Zero VOC Interior Latex Eg-Shel
Extra White
SHW-85-NA-GHS-US
101.017
ProMar® 200 HP Zero V.O.C.
Interior Acrylic Semi-Gloss
B31-1900 Series
CHARACTERISTICS
ProMar 200 HP Zero VOC Interior Acrylic is a high performance durable, professional quality, interior acrylic finish for use on walls, ceilings, and trim of primed plaster, wallboard, wood, masonry, and primed metal.
ProMar® 200 HP Zero VOC Interior Acrylic
is for commercial or light industrial projects
that require greater durability and abrasion
resistance.
MPI® compliance in Standard, High Performance, Institutional and X-Green® categories.
Color:Most Colors
To optimize hide and color development, always use the recommended P-Shade primer
Coverage:350 - 400 sq. ft. per gallon
@ 4 mils wet;
1.5 mils dry
Drying Time, @ 77°F, 50% RH:
Touch:1 Hour
Recoat:4 Hours
Drying and recoat times are temperature, humidity, and film thickness dependent
Finish:25-35 units @ 60°
Tinting with CCE only:
Base:oz/gal:Strength:
High Ref White 0-6 SherColor
Extra White 0-6 SherColor
Deep Base 4-12 SherColor
Ultradeep Base 10-12 SherColor
Extra White B31W01951(may vary by color)
V.O.C. (less exempt solvents):
less than 50 grams per litre; 0.42 lbs. per gallonAs per 40 CFR 59.406
Volume Solids:37 ± 2%
Weight Solids:47 ± 2%
Weight per Gallon:10.08 lbs
Flash Point:N/A
Vehicle Type:Acrylic
Shelf Life:36 months unopened
*Anti-microbialThis product contains agents which inhibit the growth of mold and mildew on the surface of this paint film.
COMPLIANCE
As of 10/03/2019, Complies with:
OTC Yes
OTC Phase II Yes
SCAQMD Yes
CARB Yes
CARB SCM 2007 Yes
Canada Yes
LEED® v4 & v4.1 Emissions Yes
LEED® v4 & v4.1 V.O.C.Yes
EPD-NSF® Certified Yes
MIR-Product Lens Certified No
MPI®Yes
APPLICATION
Apply at temperatures above 50°F.
No reduction needed.
Brush:
Use a nylon/polyester brush. Purdy XL Elite
Roller:
Use a 3/8 to 3/4 inch nap synthetic cover. Purdy Marathon.
For specific brushes and rollers, please refer
to our Brush and Roller Guide.
Spray—Airless
Pressure 2000 p.s.i.
Tip .017-.021 inch
APPLICATION TIPS
Make sure product is completely agitated (mechanically or manually) before use.
Priming and application of two coats at the
recommended film thickness can help where
hiding of a previous coating or application to
new drywall is a factor.
Using the same method of application and batch to touch up with as that originally used will help improve touch up.
When original application was by spray,
preconditioning of touch up paint by running
it through the spray tip will help touch up
appearance.
SPECIFICATIONS
Block:
1 coat ConFlex Block Filler*
2 coats ProMar 200 HP Zero V.O.C. Interior Latex
Drywall:
1 coat ProMar 200 Zero V.O.C. Latex Primer
2 coats ProMar 200 HP Zero V.O.C. Interior Latex
Masonry:
1 coat Loxon Concrete and Masonry Primer*2 coats ProMar 200 HP Zero V.O.C. Interior Latex
Plaster:
1 coat Loxon Concrete and Masonry Primer*
2 coats ProMar 200 HP Zero V.O.C. Interior Latex
Wood:
1 coat Premium Wall and Wood Primer*
2 coats ProMar 200 HP Zero V.O.C. Interior Latex
*These primers contain less than 50 grams per litre V.O.C.
Other primers may be appropriate.
When repainting involves a drastic color change, a coat of primer will improve the hiding performance of the topcoat color.
10/2019 www.sherwin-williams.com continued on back
ProMar® 200 HP Zero V.O.C.
Interior Acrylic Semi-Gloss
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority.
Remove all surface contamination by washing
with an appropriate cleaner, rinse thoroughly
and allow to dry. Existing peeled or checked
paint should be scraped and sanded to a
sound surface. Glossy surfaces should be
sanded dull. Stains from water, smoke, ink,
pencil, grease, etc. should be sealed with the
appropriate primer/sealer. Recognize that any
surface preparation short of total removal of the
old coating may compromise the service length
of the system.
Caulking:
Gaps between walls, ceilings, crown moldings, and other interior trim can be filled with the appropriate caulk after priming the surface.
Drywall:
Fill cracks and holes with patching paste/spackle and sand smooth. Joint compounds must be cured and sanded smooth. Remove all sanding dust.
Masonry, Concrete, Cement, Block:
All new surfaces must be cured according to the supplier’s recommendations—usually about 30 days. Remove all form release and curing agents. Rough surfaces can be filled to provide a smooth surface. If painting cannot wait 30 days, allow the surface to cure 7 days and prime the surface with Loxon Concrete & Masonry Primer.
SURFACE PREPARATION
Mildew:
Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised.
Mildew may be removed before painting by
washing with a solution of 1 part liquid bleach
and 3 parts water. Apply the solution and scrub
the mildewed area. Allow the solution to remain
on the surface for 10 minutes. Rinse thoroughly
with water and allow the surface to dry before
painting. Wear protective eyewear, waterproof
gloves, and protective clothing. Quickly wash
off any of the mixture that comes in contact with
your skin. Do not add detergents or ammonia
to the bleach/water solution.
Plaster:
Bare plaster must be cured and hard. Textured, soft, porous, or powdery plaster should be treated with a solution of 1 pint household vinegar to 1 gallon of water. Repeat until the surface is hard, rinse with clear water and allow to dry.
Wood:
Sand any exposed wood to a fresh surface. Patch all holes and imperfections with a wood filler or putty and sand smooth.
CAUTIONS
For interior use only. Protect from freezing. Non-photochemically reactive.
Before using, carefully read CAUTIONS
on label
Use only with adequate ventilation. To avoid overexposure, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air, or wear respiratory protection (NIOSH approved) or leave the area. Avoid contact with eyes and skin. Wash hands after using. Keep container closed when not in use. Do not transfer contents to other containers for storage. FIRST AID: In case of eye contact, flush thoroughly with large amounts of water. Get medical attention if irritation persists. If swallowed, call Poison Control Center, hospital emergency room, or physician immediately. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
HOTW 10/03/2019 B31W01951 08 00FRC,SP
CLEANUP INFORMATION
Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents.
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams
Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
page 1 of 3
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
08 00 [2439]
Date of Preparation
Nov 25, 2019
PRODUCT NUMBER
B31W1951
PRODUCT NAME
PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss, Extra White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B31W1951 = | Acute | Chronic |
Product Weight
10.08 lb/gal
Specific Gravity
1.21
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 53 63
Volatile Organic Compounds - U.S. EPA / Canada
B31W1951
LB/Gal g/L
Coating Density 10.08 1207
By wt By vol
Total Volatiles 52.8%62.8%
Federally exempt solvents
Water 52.7%62.7%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 47.2%37.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
B31W1951
page 2 of 3
Volatile Organic Compounds - California
B31W1951
LB/Gal g/L
Coating Density 10.08 1207
By wt By vol
Total Volatiles 52.8%62.8%
Exempt solvents
Water 52.7%62.7%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 47.2%37.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B31W1951
LB/Gal g/L
Coating Density 10.08 1207
By wt By vol
Total Volatiles 52.8%62.8%
Exempt solvents
Water 52.7%62.7%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 47.2%37.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B31W1951
By wt By vol
Total Volatiles 53.1%63.2%
VOC Content LB/Gal g/L
Total 0.03 3
Volatile Organic Compounds - EU Directive 2010/75/EU
B31W1951
By wt By vol
Total Volatiles 52.8%62.8%
VOC Content LB/Gal g/L
Total 0.00 0
B31W1951
page 3 of 3
Volatile Organic Compounds - Mexico
B31W1951
LB/Gal g/L
Coating Density 10.08 1207
By wt By vol
Total Volatiles 52.8%62.8%
Exempt solvents
Water 52.7%62.7%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 47.2%37.2%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B31W1951
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
6.53 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
Extra White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B31W1951
B31W1951Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/31/2019 Version :7 1/11
B31W1951 PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 2. Hazards identification
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Calcium Carbonate <10 1317-65-3
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Potential acute health effects
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/31/2019 Version :7 2/11
B31W1951 PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 4. First aid measures
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/31/2019 Version :7 3/11
B31W1951 PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Calcium Carbonate 1317-65-3 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
CAS #
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Extra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
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Extra White
SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.21
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9.2
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :0.141 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Conditions to avoid No specific data.
The product is stable.Chemical stability :
:
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/31/2019 Version :7 6/11
B31W1951 PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
No specific data.
:
Incompatible materials :
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable.Respiratory tract
irritation
Name Category
Not available.
Aspiration hazard
Not available.
Route of
exposure
Target organs
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
:Not available.
Potential acute health effects
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B31W1951 PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.:Ingestion
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Bioaccumulative potential
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Mobility in soil
Not available.
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SHW-85-NA-GHS-US
Section 12. Ecological information
Other adverse effects :No known significant effects or critical hazards.
Soil/water partition
coefficient (KOC)
:Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
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Extra White
SHW-85-NA-GHS-US
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
11/27/2019
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Key to abbreviations :
11/27/2019
8/31/2019
7
Hazardous Material Information System (U.S.A.)
2
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
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Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Notice to reader
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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B31W1951 PROMAR® 200 HP Zero VOC Interior Acrylic Semi-Gloss
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SHW-85-NA-GHS-US
PRO
INDUSTRIAL™
113.05A
PRO-CRYL®
UNIVERSAL PRIMER
B66W01310 Off White
B66A01320 Medium Grey
B66N01310 Red Oxide
Water Based Topcoat:
1-2 cts. Pro Industrial Acrylic Coating
or Pro Industrial Acrylic Dryfall
or Pro Industrial DTM Acrylic
or Pro Industrial Multi-Surface Acrylic
or Pro Industrial Pre-Catalyzed Epoxy
or Pro Industrial Water Based Acrolon 100
or Pro Industrial Water Base Alkyd Urethane
or Pro Industrial Water Based Catalyzed Epoxy
or Sherwin-Williams Architectural Coatings
Solvent Based Topcoat:
1-2 cts. Pro Industrial High Performance Epoxy
or Pro Industrial Urethane Alkyd
The systems listed above are representative of the product's use, other systems may be appropriate.
System Tested: (unless otherwise indicated)
Substrate: Steel
Surface Preparation: SSPC-SP10
1 ct. Pro Industrial Pro-Cryl Universal Off White Primer
1 ct. Pro Industrial Acrylic Coating
CHARACTERISTICS
Pro Industrial Pro-Cryl® Universal
Primer is an advanced technology, self
cross-linking acrylic primer. It is rust
inhibitive and was designed for both
construction and maintenance
applications. It can be used as a primer
under water-based or solvent-based high
performance topcoats.
Rust inhibitive, corrosion resistant
Single component
Early moisture resistant
Fast dry
Lower temperature application 40°F
Interior and exterior use
Suitable for use in USDA inspected
facilities
For use on properly prepared: Steel, Galvanized & Aluminum Wood
Color: Off White,
Recommended Spread Rate per coat:
Wet mils: 5.0 - 10.0
Dry mils: 1.9 - 3.8
~Coverage: 160 - 320 sq ft/gal
Approximate spreading rates are calculated on volume solids
and do not include any application loss. Note: Brush or roll
application may require multiple coats to achieve maximum
film thickness and uniformity of appearance.
Drying Time @ 6.0 mils wet 50% RH:
40°F 77°F 120°F
To touch: 2 hrs 40 min 20 min
Tack free: 8 hrs 2 hrs 1 hr
To recoat: 16 hrs 4 hrs 2 hrs
Drying time is temperature, humidity, and film thickness dependent. Finish: Low sheen
Flash Point: N/A
Shelf Life: 36 months, unopened
Store indoors at 40°F to 100°F.
Tinting: DO NOT TINT
Off White B66W01310 (may vary by color)
VOC (less exempt solvents):
<50 g/L - 0.42 lb/gal
As per 40 CFR 59.406 and SOR/2009-264, s.12
Volume Solids: 38% ± 2%
Weight Solids: 49% ± 2%
Weight per Gallon: 10.09 lb
4/2017 www.sherwin-williams.com continued on back
Adhesion:
Method: ASTM D4541
Result: 500 psi
Corrosion Weathering:
Method: ASTM D5894, 10 cycles,
3360 hours
Result: Passes
Direct Impact Resistance:
Method: ASTM D2794
Result: >140 in. lbs.
Dry Heat Resistance:
Method: ASTM D2485
Result: 200°F
Flexibility:
Method: ASTM D522, 180° bend,
1/4" mandrel
Result: Passes
Moisture Condensation Resistance:
Method: ASTM D4585, 100°F, 1250
hours
Result: Passes
Pencil Hardness:
Method: ASTM D3363
Result: B
Salt Fog Resistance:
Method: ASTM B117, 1250 hours
Result: Passes
Provides performance comparable to
products formulated to federal
specification: AA50557 and Paint
Specification: SSPC-Paint 23.
RECOMMENDED SYSTEMS
As of 04/17/2017, Complies with:
OTC Yes LEED® 09 NC,CI Yes
OTC Phase II Yes LEED® 09 CS Yes
SCAQMD Yes LEED® 09 H&S Yes
CARB Yes LEED® v4 Emissions Yes
CARB SCM 2007 Yes LEED® v4 VOC Yes
Canada Yes MPI Yes
GREENGUARD PRODUCT CERTIFIED FOR LOW CHEMICAL EMISIONS UL.COM/GG UL 2818
GOLD
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such
information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams
representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
APPLICATION
Refer to the SDS before using
Temperature: 40°F minimum
120°F maximum
(air, surface, and material)
At least 5°F above dew point
Relative humidity: 85% maximum
The following is a guide. Changes in pressures and
tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compatible with the existing environmental and application conditions.
Reducer: Water
Airless Spray
Pressure .................................... 2000 psi
Hose ............................................ 1/4" ID
Tip ...................................... .015" - .019"
Filter ......................................... 60 mesh
Reduction .................. Not recommended
Conventional Spray
Gun .......................................... Binks 95
Fluid Nozzle ........................................ 66
Air Nozzle ...................................... 63PB
Atomization Pressure .................... 60 psi
Fluid Pressure ............................... 25 psi
Reduction as needed up to 5% by volume
Brush ........................... Nylon/Polyester
Reduction .................. Not recommended
Roller ...................................3/8" woven
Reduction as needed up to 5% by volume
If specific application equipment is listed above,
equivalent equipment may be substituted.
CLEANUP INFORMATION
Clean spills and spatters immediately with
soap and warm water. Clean hands and tools
immediately after use with soap and warm
water. After cleaning, flush spray equipment
with compliant cleanup solvent to prevent
rusting of the equipment. Follow
manufacturer's safety recommendations when
using solvents.
HOTW 04/17/2017 B66W01310 01 39
KOR, FRC,SP
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or
fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other
adverse health effects, especially in children or pregnant women. Controlling exposure to lead
or other hazardous substances requires the use of proper protective equipment, such as a
properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact
your local health authority.
Surface must be clean, dry, and in sound condition. Remove all oil, dust, grease, dirt, loose rust, and other foreign material to ensure adequate adhesion.
Do not use hydrocarbon solvents for cleaning.
Iron and Steel - Minimum surface preparation is Hand Tool Cleaning per SSPC-SP2. Remove
all oil and grease from the surface per SSPC-SP1. For better performance, use Commercial
Blast Cleaning per SSPC-SP6. Self priming.
Aluminum - Remove all oil, grease, dirt, oxide and other foreign material per SSPC-SP1.Self
priming.
Galvanizing - Allow to weather a minimum of six months prior to coating. Solvent Clean per
SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates
or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least
one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP16 is
necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool
Cleaning per SSPC-SP2, prime the area the same day as cleaned. Self priming.
Previously Painted Surfaces - If in sound condition, clean the surface of all foreign material.
Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply
a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor,
additional abrasion of the surface and/or removal of the previous coating may be necessary.
Retest surface for adhesion. If paint is peeling or badly weathered, clean surface to sound
substrate and treat as a new surface as above. Recognize that any surface preparation short of
total removal of the old coating may compromise the service length of the system.
Wood - Surface must be clean, dry and sound. Prime with recommended primer. No painting
should be done immediately after a rain or during foggy weather. Knots and pitch streaks must
be scraped, sanded and spot primed before full coat of primer is applied. All nail holes or small
openings must be properly caulked.
APPLICATION PROCEDURES
Apply paint at the recommended film thickness and spreading rate as indicated on front page.
Application of coating below minimum recommended spreading rate will adversely affect
coating performance.
SAFETY PRECAUTIONS
Refer to the SDS sheets before use. FOR PROFESSIONAL USE ONLY
Published technical data and instructions are subject to change without notice. Contact your
Sherwin-Williams representative for additional technical data and instructions.
PERFORMANCE TIPS
Stripe coat crevices, welds, and sharp angles to prevent early failure in these areas. For best
results on rusty surfaces, always apply first coat by brush.
No painting should be done immediately after a rain or during foggy weather.
When using spray application, use a 50% overlap with each pass of the gun to avoid holidays,
bare areas, and pinholes. If necessary, cross spray at a right angle.
For optimal performance, this primer should be topcoated.
For exterior exposure, this primer should be topcoated within 14 days. If 14 days is exceeded
remove all surface contamination by washing with an appropriate cleaner, rinse thoroughly and
allow to dry. Finish with appropriate topcoat.
PRO INDUSTRIAL™
PRO-CRYL® UNIVERSAL PRIMER
page 1 of 4
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
02 00 [2558]
Date of Preparation
Nov 26, 2019
PRODUCT NUMBER
B66W1310
PRODUCT NAME
PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic Primer, Off White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B66W1310 = | Acute | Chronic |
Product Weight
10.09 lb/gal
Specific Gravity
1.21
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 50 60
Volatile Organic Compounds - U.S. EPA / Canada
B66W1310
LB/Gal g/L
Coating Density 10.09 1209
By wt By vol
Total Volatiles 51.1%62.3%
Federally exempt solvents
Water 49.6%60.1%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 1.3%1.8%
Percent Non-Volatile 48.9%37.7%
VOC Content LB/Gal g/L
Total 0.13 15
Less exempt solvents 0.33 39
Of solids 0.35 42
Of solids 0.02 lb/lb 0.02 kg/kg
By wt
By wt LVP-VOC 0.3%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.02
B66W1310
page 2 of 4
Volatile Organic Compounds - California
B66W1310
LB/Gal g/L
Coating Density 10.09 1209
By wt By vol
Total Volatiles 51.1%62.3%
Exempt solvents
Water 49.6%60.1%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 1.4%1.9%
Percent Non-Volatile 48.9%37.7%
VOC Content LB/Gal g/L
Total 0.14 17
Less exempt solvents 0.35 42
Of solids 0.37 45
Of solids 0.02 lb/lb 0.02 kg/kg
By wt
By wt LVP-VOC 0.4%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.02
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B66W1310
LB/Gal g/L
Coating Density 10.09 1209
By wt By vol
Total Volatiles 51.1%62.3%
Exempt solvents
Water 49.6%60.1%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 1.4%1.9%
Percent Non-Volatile 48.9%37.7%
VOC Content LB/Gal g/L
Total 0.14 17
Less exempt solvents 0.35 42
Of solids 0.37 45
Of solids 0.02 lb/lb 0.02 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B66W1310
By wt By vol
Total Volatiles 51.1%62.3%
VOC Content LB/Gal g/L
Total 0.14 17
B66W1310
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Volatile Organic Compounds - EU Directive 2010/75/EU
B66W1310
By wt By vol
Total Volatiles 50.1%60.9%
VOC Content LB/Gal g/L
Total 0.03 4
Volatile Organic Compounds - Mexico
B66W1310
LB/Gal g/L
Coating Density 10.09 1209
By wt By vol
Total Volatiles 51.1%62.3%
Exempt solvents
Water 49.6%60.1%
Non-Organic Volatiles
Ammonium Hydroxide 0.1%0.2%
Organic Volatiles 1.4%1.9%
Percent Non-Volatile 48.9%37.7%
VOC Content LB/Gal g/L
Total 0.14 17
Less exempt solvents 0.35 42
Of solids 0.37 45
Of solids 0.02 lb/lb 0.02 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B66W1310
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
7.19 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
B66W1310
page 4 of 4
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic Primer
Off White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B66W1310
B66W1310Product code :
Product Information
Telephone Number
:US / Canada: (800) 524-5979
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
:Hazard statements
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Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Avoid breathing vapor. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response :IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of
soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this
product to enter drains, sewers, wastewater treatment systems, groundwater, streams,
lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Calcium Carbonate ≥10 - <20 1317-65-3
Titanium Dioxide ≤10 13463-67-7
Polypropylene glycol alkyl phenyl ether ≤1 9064-13-5
Mineral Spirits 140-Flash ≤0.3 64742-88-7
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Specific hazards arising
from the chemical
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow
this product to enter drains, sewers, wastewater treatment systems, groundwater,
streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional
details.
Section 7. Handling and storage
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal
use the material presents a respiratory hazard, use only with adequate ventilation or
wear appropriate respirator. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers
:
Precautions for safe handling
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Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
retain product residue and can be hazardous. Do not reuse container.
Calcium Carbonate 1317-65-3 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Respirable
fraction
TWA: 10 mg/m³ 10 hours. Form: Total
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Polypropylene glycol alkyl phenyl ether 9064-13-5 None.
Mineral Spirits 140-Flash 64742-88-7 OSHA PEL (United States, 5/2018).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Occupational exposure limits (Mexico)
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow
this product to enter drains, sewers, wastewater treatment systems, groundwater,
streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional
details.
Environmental exposure
controls
:
None.
Exposure limitsCAS #
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Liquid.
Not available.
Not available.Odor
pH
Not available.Color
9.1
Not available.Odor threshold
:
:
:
:
:
:
Appearance
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.21
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :1.087 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Mutagenicity
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Calcium Carbonate Category 3 Not applicable.Respiratory tract
irritation
Mineral Spirits 140-Flash Category 3 Not applicable.Narcotic effects
Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
Mineral Spirits 140-Flash Category 1 Not determined Not determined
Aspiration hazard
Name Result
Mineral Spirits 140-Flash ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow
this product to enter drains, sewers, wastewater treatment systems, groundwater,
streams, lakes or ponds. See Environmental Data Sheet (EDS) for additional
details.
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
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Section 15. Regulatory information
U.S. Federal regulations :
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
TSCA 5(a)2 final significant new use rules: Trichloroethylene
This product contains a Significant New Use Rule (SNUR) Chemical. Do not allow this
product to enter drains, sewers, wastewater treatment systems, groundwater, streams,
lakes or ponds. See Environmental Data Sheet (EDS) for additional details.
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
2/19/2020
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
2/19/2020
11/28/2019
14
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :2/19/2020 Date of previous issue :11/28/2019 Version :14 11/12
B66W1310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic Primer
Off White
SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Key to abbreviations :
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :2/19/2020 Date of previous issue :11/28/2019 Version :14 12/12
B66W1310 PRO INDUSTRIAL™ PRO-CRYL® Universal Acrylic Primer
Off White
SHW-85-NA-GHS-US
PRO
INDUSTRIAL™
Steel*:
2 cts. Pro Industrial Acrylic
Steel:
1 ct. Pro Industrial Pro-Cryl Primer
or DTM Acrylic Primer/Finish
or Kem Bond HS
or Zinc Clad Primer
1-2 cts. Pro Industrial Acrylic
Aluminum:
1-2 cts. Pro Industrial Acrylic
Aluminum:
1 ct. Pro Industrial Pro-Cryl Primer
1-2 cts. Pro Industrial Acrylic
Concrete Block:
1 ct. Loxon Acrylic Block Surfacer
1-2 cts. Pro Industrial Acrylic
Concrete/Masonry:
1 ct. Loxon Concrete & Masonry Primer
1-2 cts. Pro Industrial Acrylic
Drywall
1 ct. ProMar 200 Zero VOC Primer
1-2 cts. Pro Industrial Acrylic
Galvanizing:
2 cts. Pro Industrial Acrylic
Prefinished Siding: (Baked-on finishes)
1 ct. DTM Bonding Primer
1-2 cts. Pro Industrial Acrylic
Wood, exterior:
1 ct. Exterior Wood Primer
1-2 cts. Pro Industrial Acrylic
Wood, interior:
1 ct. Premium Wall & Wood Primer
1-2 cts. Pro Industrial Acrylic
System Tested: (unless otherwise indicated)
Substrate: Steel
Surface Preparation: SSPC-SP10
Finish: 2 cts. Pro Industrial Acrylic, B66W00651, 6.2 DFT
CHARACTERISTICS
Pro Industrial Acrylic is an ambient
cured, single component 100% acrylic
coating. It is designed for interior and
exterior industrial and commercial
applications
Chemical resistant
Outstanding early moisture
resistance
Flash rust/early rust resistant
Suitable for use in USDA
inspected facilities
Color: most colors
Recommended Spread Rate per coat:
Wet mils: 6.0 - 12.0
Dry mils: 2.1 - 4.2
Coverage: 135 - 265 sq ft/gal
approximate
Note: Brush or roll application may require multiple
coats to achieve maximum film thickness and
uniformity of appearance.
Drying Time @ 7.0 mils wet 50% RH:
@ 50°F @ 77°F @ 120°F
To touch: 1 hr 30 min 5 min
Tack free & recoat:
8 hrs 5 hrs 15 min
Drying times are temperature, humidity, and film
thickness dependent.
Finish: 70+@60° Gloss
40-50@60° Semi-Gloss
20-30@85° Eg-Shel
Shelf Life: 36 months, unopened
Store indoors at 40°F to 100°F.
Tinting with CCE only:
Base oz/gal Strength
Extra White 0-4 100%
Deep Base 8-12 100%
Ultradeep Base 8-12 100%
Extra White B66W00611
(may vary by color)
VOC (less exempt solvents):
<50 g/L; <0.42 lb/gal
as per 40 CFR 59.406 and SOR/2009-264, s. 12
Volume Solids: 35 ± 2%
Weight Solids: 44 ± 2%
Weight per Gallon: 9.5 lb/gal ±2%
Flash Point: N/A
03/2018 www.sherwin-williams.com continued on back
Adhesion:
Method: ASTM D4541
Result: 1324 psi
Corrosion Weathering *:
Method: ASTM D5894, 1500 hours, 5
cycles
Result: Rating 10, per ASTM D714
for blistering
Rating 9.5 per ASTM D1654
for corrosion
Direct Impact Resistance:
Method: ASTM D2794
Result: >176 in. lb
Dry Heat Resistance:
Method: ASTM D2485
Result: 300°F
Flexibility:
Method: ASTM D522, 180° bend,
1/8" mandrel
Result: Passes
Humidity Resistance*:
Method: ASTM D4585, 1480 hours
Result: Rating 10 per ASTM D714 for
blistering
Rating 10 per ASTM D1654
for corrosion
Pencil Hardness:
Method: ASTM D3363
Result: 3B
RECOMMENDED SYSTEMS
*Application of coating on unprimed steel may cause pinpoint rusting. Safety Colors, Deep Base, and
Ultradeep colors require a prime coat for maximum durability, adhesion, and corrosion protection.
GREENGUARD
PRODUCT CERTIFIED FOR
LOW CHEMICAL EMISSIONS
UL.COM/GG
UL 2818
GOLD
113.03
ACRYLIC
B66-600 SERIES GLOSS
B66-650 SERIES SEMI-GLOSS
B66-660 SERIES EG-SHEL As of 03/21/2018, Complies with:
OTC Yes LEED® 09 NC, CI Yes
OTC Phase II Yes LEED® 09 CS Yes
SCAQMD Yes LEED® V4 Emissions Yes
CARB Yes LEED® V4 VOC Yes
CARB SCM 2007 Yes
Canada Yes MPI Yes
*over Pro Industrial Pro-Cryl Primer
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such
information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams
representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
APPLICATION
Refer to the SDS before use.
Temperature: 50°F minimum
120°F maximum
(Air, surface, and material)
At least 5°F above dew point
Relative humidity: 85% maximum
The following is a guide. Changes in
pressures and tip sizes may be needed for
proper spray characteristics. Always purge
spray equipment before use with listed
reducer. Any reduction must be compatible
with the existing environmental and
application conditions.
Reducer Water
Airless Spray
Pressure ........................................ 1500 psi
Hose ................................................. 1/4" ID
Tip ........................................... .017" - .021"
Filter .............................................. 60 mesh
Reduction ...................... Not recommended
Conventional Spray
Gun ................................................ Binks 95
Fluid Nozzle ............................................ 66
Air Nozzle ........................................... 63PB
Atomization Pressure ........................ 50 psi
Fluid Pressure .............................. 15-20 psi
Reduction ........ As needed up to 12½%by volume
Brush .............................. Nylon / polyester
Reduction ...................... Not recommended
Roller ....................................... 3/8" woven
Reduction ...................... Not recommended
If specific application equipment is listed above,
equivalent equipment may be substituted.
CLEANUP INFORMATION
Clean spills and spatters immediately with
soap and warm water. Clean hands and tools
immediately after use with soap and warm
water. After cleaning, flush spray equipment
with compliant cleanup solvent to prevent
rusting of the equipment. Follow
manufacturer's safety recommendations when using solvents.
HOTW 03/21/2018 B66W00611 17 00
KOR, FRC, SP
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or
fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other
adverse health effects, especially in children or pregnant women. Controlling exposure to lead
or other hazardous substances requires the use of proper protective equipment, such as a
properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact
your local health authority.
Do not use hydrocarbon solvents for cleaning.
Iron & Steel - Minimum surface preparation is Hand Tool Clean per SSPC-SP2. Remove all oil
and grease from surface per SSPC-SP1. For better performance, use Commercial Blast
Cleaning per SSPC-SP6. Primer recommended for best performance.
Aluminum - Remove all oil, grease, dirt, oxide and other foreign material per SSPC-SP1.
Galvanizing - Allow to weather a minimum of six months prior to coating. Solvent Clean per
SSPC-SP1. When weathering is not possible, or the surface has been treated with chromates
or silicates, first Solvent Clean per SSPC-SP1 and apply a test patch. Allow paint to dry at least
one week before testing adhesion. If adhesion is poor, brush blasting per SSPC-SP16 is
necessary to remove these treatments. Rusty galvanizing requires a minimum of Hand Tool
Cleaning per SSPC-SP2, prime the area the same day as cleaned.
Concrete and Masonry - For surface preparation, refer to SSPC-SP13/NACE 6 or ICRI 03732, CSP 1-3. Surfaces should be thoroughly cleaned and dry. Surface temperatures must
be at least 55°F before filling. If required for a smoother finish, use the recommended filler/
surfacer. The filler/surfacer must be thoroughly dry before topcoating per manufacturer's
recommendations. Weathered masonry and soft or porous cement board must be brush blasted
or power tool cleaned to remove loosely adhering contamination and to get to a hard, firm
surface. Apply one coat Loxon Conditioner, following label recommendations.
Wood - Surface must be clean, dry and sound. Prime with recommended primer. No painting
should be done immediately after a rain or during foggy weather. Knots and pitch streaks must
be scraped, sanded and spot primed before full coat of primer is applied. All nail holes or small
openings must be properly caulked.
Previously Painted Surfaces - If in sound condition, clean the surface of all foreign material.
Smooth, hard or glossy coatings and surfaces should be dulled by abrading the surface. Apply
a test area, allowing paint to dry one week before testing adhesion. If adhesion is poor, additional abrasion of the surface and/or removal of the previous coating may be necessary.
Retest surface for adhesion. If paint is peeling or badly weathered, clean surface to sound
substrate and treat as a new surface as above. Recognize that any surface preparation short of
total removal of the old coating may compromise the service length of the system.
APPLICATION PROCEDURES
Apply paint at the recommended film thickness and spreading rate as indicated on front page.
Application of coating above maximum or below minimum recommended spreading rate may
adversely affect coating performance.
SAFETY PRECAUTIONS
Refer to the SDS sheets before use. FOR PROFESSIONAL USE ONLY.
Published technical data and instructions are subject to change without notice. Contact your
Sherwin-Williams representative for additional technical data and instructions.
PRO INDUSTRIAL™
ACRYLIC
page 1 of 4
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
22 00 [1788]
Date of Preparation
Nov 26, 2019
PRODUCT NUMBER
B66W651
PRODUCT NAME
PRO INDUSTRIAL™ Acrylic - Semi-Gloss, Extra White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
B66W651 = | Acute | Chronic |
Product Weight
9.55 lb/gal
Specific Gravity
1.15
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 54 62
Volatile Organic Compounds - U.S. EPA / Canada
B66W651
LB/Gal g/L
Coating Density 9.55 1144
By wt By vol
Total Volatiles 54.7%63.0%
Federally exempt solvents
Water 54.3%62.4%
Non-Organic Volatiles
Ammonium Hydroxide 0.4%0.5%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 45.3%37.0%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
B66W651
page 2 of 4
Volatile Organic Compounds - California
B66W651
LB/Gal g/L
Coating Density 9.55 1144
By wt By vol
Total Volatiles 54.7%63.0%
Exempt solvents
Water 54.3%62.4%
Non-Organic Volatiles
Ammonium Hydroxide 0.4%0.5%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 45.3%37.0%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
B66W651
LB/Gal g/L
Coating Density 9.55 1144
By wt By vol
Total Volatiles 54.7%63.0%
Exempt solvents
Water 54.3%62.4%
Non-Organic Volatiles
Ammonium Hydroxide 0.4%0.5%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 45.3%37.0%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
B66W651
By wt By vol
Total Volatiles 54.7%63.0%
VOC Content LB/Gal g/L
Total 0.00 0
B66W651
page 3 of 4
Volatile Organic Compounds - EU Directive 2010/75/EU
B66W651
By wt By vol
Total Volatiles 54.7%62.9%
VOC Content LB/Gal g/L
Total 0.00 0
Volatile Organic Compounds - Mexico
B66W651
LB/Gal g/L
Coating Density 9.55 1144
By wt By vol
Total Volatiles 54.7%63.0%
Exempt solvents
Water 54.3%62.4%
Non-Organic Volatiles
Ammonium Hydroxide 0.4%0.5%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 45.3%37.0%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 1
Of solids 0.00 1
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
B66W651
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
7.02 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
B66W651
page 4 of 4
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
PRO INDUSTRIAL™ Acrylic - Semi-Gloss
Extra White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
B66W651
B66W651Product code :
Product Information
Telephone Number
:US / Canada: (800) 524-5979
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity:
1.7%
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
1.7%
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 1.7%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
May cause an allergic skin reaction.
Suspected of causing cancer.
:Hazard statements
Date of issue/Date of revision :12/27/2019 Date of previous issue :12/11/2019 Version :13.02 1/11
B66W651 PRO INDUSTRIAL™ Acrylic - Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Avoid breathing vapor. Contaminated work clothing must not
be allowed out of the workplace.
Response :IF exposed or concerned: Get medical attention. IF ON SKIN: Wash with plenty of
soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Polypropylene glycol alkyl phenyl ether ≤3 9064-13-5
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision :12/27/2019 Date of previous issue :12/11/2019 Version :13.02 2/11
B66W651 PRO INDUSTRIAL™ Acrylic - Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :May cause an allergic skin reaction.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Date of issue/Date of revision :12/27/2019 Date of previous issue :12/11/2019 Version :13.02 3/11
B66W651 PRO INDUSTRIAL™ Acrylic - Semi-Gloss
Extra White
SHW-85-NA-GHS-US
Section 5. Fire-fighting measures
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. If during normal
use the material presents a respiratory hazard, use only with adequate ventilation or
wear appropriate respirator. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
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Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Polypropylene glycol alkyl phenyl ether 9064-13-5 None.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Control parameters
Individual protection measures
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.14
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
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Section 9. Physical and chemical properties
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt):
Decomposition temperature :Not available.
Heat of combustion :0.76 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Not available.
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :May cause an allergic skin reaction.
No known significant effects or critical hazards.:Eye contact
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
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Section 11. Toxicological information
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Environmental
hazards
No.No.
TDG
Classification
Not regulated.
-
-
-
No.
Mexico
Classification
Not regulated.
-
-
-
No.
IATA
Not regulated.
-
-
-
No.
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Section 14. Transport information
--Additional
information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
--
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
-
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
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Section 16. Other information
12/27/2019
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
12/27/2019
12/11/2019
13.02
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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115.02
Loxon®
Concrete and Masonry Primer/Sealer
U.S. LX02W0050 White, Canada LX02WQ050 White
CHARACTERISTICS
Loxon Concrete & Masonry Primer/Sealer is an acrylic coating specifically engineered for interior and exterior, above-grade, masonry surfaces requiring a high performance primer. It is highly alkali and efflorescence resistant and can be applied to surfaces with a pH of 6 to 13.
Loxon Concrete & Masonry Primer/Sealer:
Seals and adheres to concrete, brick, stucco and plaster
Conditions porous masonry surfaces
Use on above grade masonry surfaces for a long-lasting finish
Apply to masonry and concrete surfaces that are at least 7 days old.
Prevents harm to subsequent coatings by alkalies in the substrate
For use on these surfaces:
Concrete, Concrete Block, Brick, Stucco, Fiber Cement Siding, Plaster, Mortar, EIFS Exterior Wall Cladding
Color:White
Coverage:
Wet mils:5.3-8.0
Dry mils:2.1-3.2
Coverage sq.ft. per gallon 200-300 Coverage on porous & rough stucco 80 square feet per gallon
Drying Schedule 77° F @ 50% RH:@ 77°FTouch:4 hours
Recoat: 24 hours
Air and surface temperatures must not drop below 40°F for 48 hours after application.
Drying and recoat times are temperature, humidity and film thickness dependent.
Finish:0-10 units @85°
Tinting with CCE only:
For best topcoat color development, use the recommended “P”-shade primer. If desired, up to 4 oz. per gallon of ColorCast Ecotoners can be used to approximate the topcoat color. Check color before use.
White LX02W0050
V.O.C. (less exempt solvents):
less than 50 grams per litre; 0.42 lbs.per gallon
As per 40 CFR 59.406Volume Solids:40 ± 2% Weight Solids:55 ± 2% Weight per Gallon:10.92 lbFlash Point:NAVehicle Type:AcrylicShelf Life:36 months,unopened
COMPLIANCE
As of 12/11/2019, Complies with:
OTC YesOTC Phase II Yes
SCAQMD YesCARBYesCARB SCM 2007 YesCanadaYes
LEED® v4 & v4.1 Emissions Yes
LEED® v4 & v4.1 V.O.C.YesEPD-NSF® Certified YesMIR-Product Lens Certified Yes
MPI Yes
APPLICATION
Temperature:
minimum 40°F
The following is a guide. Changes in pressures and tip sizes may be needed for proper spray characteristics. Always purge spray equipment before use with listed reducer. Any reduction must be compatible with the existing environmental and application conditions.
Reducer:No reduction necessary
Airless Spray:
Pressure 2000-2700 p.s.i.
Tip .019 inch
Brush Use a nylon/polyester brush.
Roller Cover Use a 1/2 to 11/2 inch nap synthetic cover.
Spray and backroll on porous & rough stucco to achieve required film build and a pin-hole free surface.
For porous block a coat of Loxon Acrylic Block Surfacer is required to achieve a pinhole free surface.
Apply at temperatures above 40°F. When the air temperature is at 40°F, substrates may be colder; prior to painting, check to be sure the air, surface, and material temperature are above 40°F and at least 5°F above the dew point. Avoid using if rain or snow is expected within 4-6 hours.
Do not apply at air or surface temperatures below 40°F or when air or surface temperatures may drop below 40°F within 48 hours.
Do not paint in direct sun or on a hot surface.
Do not reduce.
May be applied to damp but not to wet surfaces.
APPLICATION TIPS
Apply paint at the recommended film thickness and spreading rate as indicated on the page. Application of coating below minimum recommended spreading rate may adversely affect the coating systems performance.
When spot priming on some surfaces, a non-uniform appearance of the final coat may result, due to differences in holdout between primed and unprimed areas. To avoid this, prime the entire surface rather than spot priming.
For optimal performance, this primer/sealer must be topcoated with a latex, alkyd/oil, water based epoxy, or solvent based epoxy coating on architectural applications.
For exterior use, this primer/sealer must be topcoated within 14 days to prevent degradation due to weathering.
RECOMMENDED SYSTEMS
Concrete, Masonry, Cement1 coat Loxon Concrete and Masonry Primer
2 coats Appropriate topcoat
Stucco, Fiber Cement Siding, EIFS:
1 coat Loxon Concrete and Masonry Primer2 coats Appropriate topcoat
Recommended Architectural Topcoats:
A-100 Exterior Latex
Duration Exterior & Duration Home Interior
Emerald Exterior & Interior
Loxon Masonry Coatings
SuperPaint Exterior & Interior
ProClassic Interior
ProMar Interior
Recommended Industrial Topcoats:
Industrial Enamels
Pro Industrial Series
Steel Master 9500 Silicone Alkyd
Water Based Catalyzed Epoxy
Industrial finishes have been tested for architectural applications only. Loxon Concrete and Masonry Primer has not been tested in environments subject to chemical attack. Any recommendations for use in such areas must follow a thorough evaluation of the effects of the environment on the Loxon Concrete and Masonry Primer and topcoat system.
12/2019 www.sherwin-williams.com continued on back
Loxon®
Concrete and Masonry Primer/Sealer
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority.
Remove all surface contamination by washing with an appropriate cleaner, rinse thoroughly and allow to dry. Scrape and sand peeled or checked paint to a sound surface. Sand glossy surfaces dull. Seal stains from water, smoke, ink, pencil, grease, etc. with the appropriate primer/sealer. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of the system.
Masonry, Concrete, Stucco:
All new surfaces must cure for at least 7 days. Remove all form release and curing agents. Pressure clean to remove all dirt, dust, grease, oil, loose particles, laitance, foreign material, peeling and defective coatings, chalks, etc. Allow the surface to dry before proceeding. Repair cracks, voids, and other holes with an appropriate patching compound or sealant.
Concrete and mortar must be cured at least 7 days at 75°F. Moisture content must be 15% or lower. On tilt-up and poured-in-place concrete, commercial detergents and sandblasting may be necessary to remove sealers, release compounds, and to provide an anchor pattern. Fill bugholes, air pockets and other voids with an elastomeric patch or sealant.
Caulking
Fill gaps between walls, ceilings, crown moldings, and other trim with the appropriate caulk after priming the surface.
SURFACE PREPARATION
Mildew:
Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised.
Mildew may be removed before painting by washing with a solution of 1 part liquid bleach and 3 parts water. Apply the solution and scrub the mildewed area. Allow the solution to remain on the surface for 10 minutes. Rinse thoroughly with water and allow the surface to dry before painting. Wear protective eyewear, waterproof gloves, and protective clothing. Quickly wash off any of the mixture that comes in contact with your skin. Do not add detergents or ammonia to the bleach/water solution.
PHYSICAL PROPERTIES
Do not paint on wet surfaces.
LX02W0050
Water Vapor Permeance (US) : 26.67 perms
Method:ASTM D1653 grains/(hr ft2 in Hg)
Flexibility:Method:ASTM D522, method B, 180° bend, 1/8 inch mandrel
Result:Pass
Alkali Resistance:
Method:ASTM D1308
Result:Pass
Mildew Resistance:
Method:ASTM D3273/D3274
Result:Pass
Efflorescence:Method:ASTM D7072-04
Result:None
CAUTIONS
For interior or exterior use.
Protect from freezing.
Do not apply at temperatures below 40°F. Air and surface temperatures must not drop below 40°F for 48 hours after application.
Before using, carefully read CAUTIONS on label.
CRYSTALLINE SILICA, ZINC. Use only with adequate ventilation. To avoid overexposure, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air, or wear respiratory protection (NIOSH approved) or leave the area. Adequate ventilation required when sanding or abrading the dried film. If adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer’s directions for respirator use. Avoid contact with eyes and skin. Wash hands after using. Keep container closed when not in use. Do not transfer contents to other containers for storage. FIRST AID: In case of eye contact, flush thoroughly with large amounts of water. Get medical attention if irritation persists. If swallowed, call Poison Control Center, hospital emergency room, or physician immediately. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release crystalline silica which has been shown to cause lung damage and cancer under long term exposure. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
HOTW 12/11/2019 LX02W0050 38 46FRC, SP
CLEANUP INFORMATION
Clean spills, spatters, hands and tools immediately after use with soap and warm water. After cleaning, flush spray equipment with a compliant cleanup solvent to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents.
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
page 1 of 4
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
38 00 [1029]
Date of Preparation
Nov 8, 2019
PRODUCT NUMBER
LX02W50
PRODUCT NAME
LOXON® Concrete & Masonry Primer/Sealer, White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
LX02W50 = | Acute | Chronic |
Product Weight
10.92 lb/gal
Specific Gravity
1.31
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 43 58
Regulated Compounds
SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Zinc (as Zn)N Y Y N 1
Zinc Compound N N Y N 1
Volatile Organic Compounds - U.S. EPA / Canada
LX02W50
LB/Gal g/L
Coating Density 10.92 1308
By wt By vol
Total Volatiles 44.7%59.8%
Federally exempt solvents
Water 43.0%57.5%
Non-Organic Volatiles
Ammonium Hydroxide 0.2%0.3%
Organic Volatiles 1.5%2.0%
Percent Non-Volatile 55.3%40.2%
VOC Content LB/Gal g/L
Total 0.16 19
Less exempt solvents 0.39 46
Of solids 0.41 49
Of solids 0.02 lb/lb 0.02 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.02
LX02W50
page 2 of 4
Volatile Organic Compounds - California
LX02W50
LB/Gal g/L
Coating Density 10.92 1308
By wt By vol
Total Volatiles 44.7%59.8%
Exempt solvents
Water 43.0%57.5%
Non-Organic Volatiles
Ammonium Hydroxide 0.2%0.3%
Organic Volatiles 1.5%2.0%
Percent Non-Volatile 55.3%40.2%
VOC Content LB/Gal g/L
Total 0.16 19
Less exempt solvents 0.39 46
Of solids 0.41 49
Of solids 0.02 lb/lb 0.02 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.02
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
LX02W50
LB/Gal g/L
Coating Density 10.92 1308
By wt By vol
Total Volatiles 44.7%59.8%
Exempt solvents
Water 43.0%57.5%
Non-Organic Volatiles
Ammonium Hydroxide 0.2%0.3%
Organic Volatiles 1.5%2.0%
Percent Non-Volatile 55.3%40.2%
VOC Content LB/Gal g/L
Total 0.16 19
Less exempt solvents 0.39 46
Of solids 0.41 49
Of solids 0.02 lb/lb 0.02 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
LX02W50
By wt By vol
Total Volatiles 43.8%58.6%
VOC Content LB/Gal g/L
Total 0.06 8
LX02W50
page 3 of 4
Volatile Organic Compounds - EU Directive 2010/75/EU
LX02W50
By wt By vol
Total Volatiles 43.8%58.6%
VOC Content LB/Gal g/L
Total 0.06 7
Volatile Organic Compounds - Mexico
LX02W50
LB/Gal g/L
Coating Density 10.92 1308
By wt By vol
Total Volatiles 44.7%59.8%
Exempt solvents
Water 43.0%57.5%
Non-Organic Volatiles
Ammonium Hydroxide 0.2%0.3%
Organic Volatiles 1.5%2.0%
Percent Non-Volatile 55.3%40.2%
VOC Content LB/Gal g/L
Total 0.16 19
Less exempt solvents 0.39 46
Of solids 0.41 49
Of solids 0.02 lb/lb 0.02 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
LX02W50
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
8.01 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
LX02W50
page 4 of 4
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
LOXON® Concrete & Masonry Primer/Sealer
White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
LX02W50
LX02W50Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity:
9.2%
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
9.2%
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 9.2%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
May cause cancer.
Causes damage to organs through prolonged or repeated exposure.
:Hazard statements
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Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. Adequate ventilation required when
sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an
approved particulate respirator (NIOSH approved). Follow respirator manufacturer's
directions for respirator use. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica
which has been shown to cause lung damage and cancer under long term exposure.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Crystalline Silica, respirable powder ≤10 14808-60-7
Zinc Oxide ≤3 1314-13-2
Heavy Paraffinic Oil ≤1 64742-65-0
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Inhalation :
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Skin contact
Ingestion :
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
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Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Crystalline Silica, respirable powder 14808-60-7 OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:
Respirable
OSHA PEL (United States, 5/2018).
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2019).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2016).
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust
Zinc Oxide 1314-13-2 NIOSH REL (United States, 10/2016).
CEIL: 15 mg/m³ Form: Dust
TWA: 5 mg/m³ 10 hours. Form: Dust and
fumes
STEL: 10 mg/m³ 15 minutes. Form: Fume
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
Heavy Paraffinic Oil 64742-65-0 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2019).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Occupational exposure limits (Canada)
CAS #
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Section 8. Exposure controls/personal protection
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Quartz 14808-60-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 0.1 mg/m³ 8 hours. Form:
Respirable dust.
CA Ontario Provincial (Canada, 1/2018).
TWA: 0.1 mg/m³ 8 hours. Form: Respirable
fraction.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 0.025 mg/m³ 8 hours. Form:
Respirable particulate
CA Saskatchewan Provincial (Canada,
7/2013).
TWA: 0.05 mg/m³ 8 hours. Form: respirable
fraction
Zinc Oxide 1314-13-2 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form:
Respirable
15 min OEL: 10 mg/m³ 15 minutes. Form:
Respirable
CA British Columbia Provincial (Canada,
5/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
STEL: 10 mg/m³ 15 minutes. Form:
Respirable
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction.
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: fume
STEV: 10 mg/m³ 15 minutes. Form: fume
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 10 mg/m³ 15 minutes. Form:
respirable dust and fume
TWA: 2 mg/m³ 8 hours. Form: respirable
Ingredient name Exposure limitsCAS #
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
dust and fume
Environmental exposure
controls
:
Crystalline Silica, respirable powder 14808-60-7 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
Zinc Oxide 1314-13-2 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
Exposure limits
Occupational exposure limits (Mexico)
CAS #
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Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.31
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9.5
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :1.54 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Section 11. Toxicological information
Acute toxicity
Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Zinc Oxide Eyes - Mild irritant Rabbit -24 hours 500
mg
-
Skin - Mild irritant Rabbit -24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Name Category
Crystalline Silica, respirable powder Category 1 Inhalation Not determined
Aspiration hazard
Name Result
Heavy Paraffinic Oil ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Crystalline Silica, respirable
powder
-1 Known to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
Causes damage to organs through prolonged or repeated exposure.General :
May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Zinc Oxide Acute IC50 1.85 mg/l Marine water Algae - Skeletonema costatum 96 hours
Acute IC50 46 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata - Exponential growth
phase
72 hours
Acute LC50 98 µg/l Fresh water Daphnia - Daphnia magna -
Neonate
48 hours
Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Not available.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Zinc Oxide -28960 high
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No.No.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision :11/27/2019 Date of previous issue :11/7/2019 Version :8 11/13
LX02W50 LOXON® Concrete & Masonry Primer/Sealer
White
SHW-85-NA-GHS-US
Section 14. Transport information
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
11/27/2019
History
Date of printing
Date of issue/Date of
revision
:
:11/27/2019
Hazardous Material Information System (U.S.A.)
3
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 1A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Calculation method
Procedure used to derive the classification
Classification Justification
Date of issue/Date of revision :11/27/2019 Date of previous issue :11/7/2019 Version :8 12/13
LX02W50 LOXON® Concrete & Masonry Primer/Sealer
White
SHW-85-NA-GHS-US
Section 16. Other information
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Date of previous issue
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
11/7/2019
8
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :11/27/2019 Date of previous issue :11/7/2019 Version :8 13/13
LX02W50 LOXON® Concrete & Masonry Primer/Sealer
White
SHW-85-NA-GHS-US
116.31
ConFlex®
7% Siloxane Water Repellent
CF31T0007 Clear
CHARACTERISTICS
ConFlex 7% Siloxane Water Repellent is a clear siloxane water repellent designed to weatherproof old and new concrete and masonry against nature’s destructive forces, providing a long lasting, breathable barrier which exhibits excellent resistance to water, airborne dust and dirt, salt, acid rain, efflorescence, alkali, freeze/thaw damage and spalling.
ConFlex 7% Siloxane Water Repellent protects against damage resulting from moisture intrusion.
ConFlex 7% Siloxane Water Repellent does not mar glass or metal flashing.
Color:ClearCoverage:Approximate total coverage rates:
sq. ft./gallon
Smooth Precast Concrete 125-175Porous Concrete, Brick (clay), Bridge Decks 100-150
Decorative Block, Stucco 50-150 Steel Troweled Concrete 150-200
Split Face Block, Fluted 25-75
Concrete Block 75-125
Coverage will vary depending on the porosity and texture of the substrate.
If a second coat is required to uniform the application, this product MUST be applied wet-on-wet.
Drying Schedule @ 50% RH: temperature and humidity dependentTouch 3 hours
Clear CF31T0007
V.O.C. (less exempt solvents):
less than 50 grams per litre; .42 lbs. per gallon
As per 40 CFR 59.406Active Content:7 ± 2% Weight per Gallon:8.26 Flash Point:N/A
Vehicle Type:SiloxaneShelf Life:12 months,unopened
Sherwin-Williams Technical Data for the Siloxane Water Repellent reports Active Content which is based off ASTM D5095 - Standard Test Method for Determination of the Nonvolatile Content in Silanes, Siloxanes, and Silane-Siloxane Blends Used in Masonry Water Repellents Treatments. A catalyst is used to react the treatment and some active content is consumed as the treatment polymerizes yielding a lower solids value. The total solids for this product by ASTM D5095 is 5% ± 2%.
COMPLIANCE
As of 08/29/2019, Complies with:
OTC YesOTC Phase II YesSCAQMDYesCARBYesCARB SCM 2007 YesCanadaYes
LEED® v4 & v4.1 Emissions No
LEED® v4 & v4.1 V.O.C.YesEPD-NSF® Certified NoMIR-Product Lens Certified NoMPI Yes
APPLICATION
Temperature: Air and surface temperature must be between 50° and 90°F.
A single flood coat is recommended, if a second coat is needed, it MUST be applied as a wet-on-wet application or there may be intercoat adhesion problems.
Surface texture determines actual coverage.
Stir thoroughly before and during application.
Protect against rain for 4 to 5 hours to allow the water repellent to become effective.
Allow 7 days for the product to fully react before evaluating performance.
Reducer:No reduction necessary
If surface is damp or wet from weather or cleaning, allow the surface to dry thoroughly before applying any coating.
Apply by low pressure airless sprayer or pump-up sprayer. The best results are achieved when working with low spraying pressures so the impregnating solution is applied in the form of droplets rather than a mist. Use the flood method.
APPLICATION TIPS
Vertical surfaces - saturate or “flood”, allowing the material to run down 8 to 10 inches. Work from the bottom up and in sections small enough to allow the run down to remain “wet” as application continues.
Horizontal surfaces - coat with enough material to allow it to stand for a few seconds before penetrating.
Interruption of Work: Upon drying, treated surfaces appear identical to untreated surfaces. It is possible areas could remain untreated if work is interrupted. It is advisable to stop application on a corner joint or any other obvious marker so the applicator can begin where application had previously ceased.
RECOMMENDED SYSTEMS
Most Concrete and Masonry surfaces including:
• Stadium Supports
• Bridges and Bridge Structures
• Parking Garages, Traffic Sound Barriers
• Driveways, Sidewalks
• Concrete & brick patios
Use on:
• Tilt-up and poured-in-place walls
• Concrete, Split faced & Fluted block
• Brick (clay or cement)
• Stucco, Mortar
Do not use on asphalt surfaces.
Not for immersion service.
08/2019 www.sherwin-williams.com continued on back
ConFlex®
7% Siloxane Water Repellent
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority.
Concrete, Stucco :
If needed, pressure clean with a minimum of 2100 psi to remove all dirt, dust, grease, oil, loose particles, laitance, foreign material, coatings, chalk, form release agents, moisture curing membranes, mildew, etc. Allow the surface to dry thoroughly. Concrete and mortar must be cured at least 7 days at 75°F. On tilt-up and poured-in-place concrete, commercial detergents and sandblasting may be necessary to remove sealers, release compounds, and to provide an anchor pattern.
For very smooth surfaces (troweled surfaces with no porosity) use Concrete Etching Solution at full strength to open up the surface to allow this to penetrate into the surface. For smooth-troweled concrete with some porosity, 1 part Concrete Etching Solution to two parts water should be used.
Only etch horizontal concrete, follow label directions carefully, including neutralization.
Prepared concrete should have a pH between 7 and 10.
Because water will collect in low spots and may deposit etching and cleaning residue, it is recommended that, if needed, the surface be vacuumed to remove any remaining water.
Repair any loose or disintegrated mortar and allow it to cure before application. Repaired areas may be noticeable through this clear coating.
•Use caution when preparing the substrate to create a uniform surface.
•Cracks, crevices, and through-wall openings must be patched using an elastomeric sealant or patch.
•Fill voids and openings around window and doors using an elastomeric sealant or patch.
•Stripe coat all inside and outside corners and edges with ConFlex Siloxane Water RepellentTesting: Due to the wide variety of substrates, preparation methods, application methods and environments, the customer should test the product in an inconspicuous spot for adhesion and compatibility prior to full scale application.
To determine if the surface is sealed with another coating or a curing compound, sprinkle water onto the surface. If the water is absorbed and the surface becomes darker, the surface is not sealed. If the water beads up, there is a coating or curing compound that must be removed to allow the water prepellent to penetrate. It is crucial to ensure proper penetration of the coating.
Remove all surface contamination by washing with an appropriate cleaner, rinse thoroughly and allow to dry. Remove all existing paint.
SURFACE PREPARATION
Mildew:
Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised.
Mildew may be removed before painting by washing with a solution of 1 part liquid bleach and 3 parts water. Apply the solution and scrub the mildewed area. Allow the solution to remain on the surface for 10 minutes. Rinse thoroughly with water and allow the surface to dry before painting. Wear protective eyewear, waterproof gloves, and protective clothing. Quickly wash off any of the mixture that comes in contact with your skin. Do not add detergents or ammonia to the bleach/water solution.
PERFORMANCE TESTING
CF31T0007
ASTM E 514, Water Permeance of Masonry.
Reduction in Leakage Rate62%ConFlex Siloxane (average)
Water Repellency:76%Rilem Tube (72 hrs)
81%Immersion (3 day)
Alkali Resistance Tests:
Each was allowed to react for 24 hours under a watch glass, washed with water, allowed to recover for 30 minutes then observed.
Alkali:5% NaOH and 10% NaOH
Result: Pass
CAUTIONS
ConFlex 7% Siloxane Water Repellent is not recommended for topcoating over film-forming paints, stains, or sealers.
ConFlex 7% Siloxane Water Repellent will not prevent water penetration through unsound or cracked surfaces or structures with defective structural waterproofing, caulking or flashing.
Not for use on marble, limestone, or other forms of calcium carbonate. These surfaces can be very smooth, this product may not penetrate into these surfaces and provide the water repellency needed.
ConFlex 7% Siloxane Water Repellent can be slippery for several hours after application. When applied to traffic bearing areas, do not open the treated areas until the product has fully dried.
Do not use below grade.
For atmospheric use only.
Do not use on asphalt surfaces.
Not for immersion service.
Before using, carefully read CAUTIONS on label.
Use only with adequate ventilation. To avoid overexposure, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air, or wear respiratory protection (NIOSH approved) or leave the area. Avoid contact with eyes and skin. Wash hands after using. Keep container closed when not in use. Do not transfer contents to other containers for storage. FIRST AID: In case of eye contact, flush thoroughly with large amounts of water. Get medical attention if irritation persists. If swallowed, call Poison Control Center, hospital emergency room, or physician immediately. WARNING: This product contains chemicals known to the State of California to cause birth defects or other reproductive harm. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN.
HOTW 08/29/2019 CF31T0007 09 00FRC, SP
CLEANUP INFORMATION
Clean spills and spatters, hands and tools immediately with soap and warm water. After cleaning, flush spray equipment with compliant cleanup solvents to prevent rusting of the equipment. Follow manufacturer’s safety recommendations when using solvents
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
page 1 of 3
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
09 00 [1708]
Date of Preparation
Nov 25, 2019
PRODUCT NUMBER
CF31T0007
PRODUCT NAME
ConFlex™ 7% Siloxane Water Repellent
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
CF31T0007 = | Chronic |
Product Weight
8.26 lb/gal
Specific Gravity
0.99
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 92 91
Volatile Organic Compounds - U.S. EPA / Canada
CF31T0007
LB/Gal g/L
Coating Density 8.26 989
By wt By vol
Total Volatiles 92.0%91.3%
Federally exempt solvents
Water 92.0%91.3%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 8.0%8.7%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.00
CF31T0007
page 2 of 3
Volatile Organic Compounds - California
CF31T0007
LB/Gal g/L
Coating Density 8.26 989
By wt By vol
Total Volatiles 92.0%91.3%
Exempt solvents
Water 92.0%91.3%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 8.0%8.7%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.00
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
CF31T0007
LB/Gal g/L
Coating Density 8.26 989
By wt By vol
Total Volatiles 92.0%91.3%
Exempt solvents
Water 92.0%91.3%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 8.0%8.7%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
CF31T0007
By wt By vol
Total Volatiles 92.0%91.3%
VOC Content LB/Gal g/L
Total 0.00 0
Volatile Organic Compounds - EU Directive 2010/75/EU
CF31T0007
By wt By vol
Total Volatiles 92.0%91.3%
VOC Content LB/Gal g/L
Total 0.00 0
CF31T0007
page 3 of 3
Volatile Organic Compounds - Mexico
CF31T0007
LB/Gal g/L
Coating Density 8.26 989
By wt By vol
Total Volatiles 92.0%91.3%
Exempt solvents
Water 92.0%91.3%
Organic Volatiles 0.0%0.0%
Percent Non-Volatile 8.0%8.7%
VOC Content LB/Gal g/L
Total 0.00 0
Less exempt solvents 0.00 0
Of solids 0.00 0
Of solids 0.00 lb/lb 0.00 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
CF31T0007
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
9.68 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
ConFlex™ 7% Siloxane Water Repellent
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
CF31T0007
CF31T0007Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
Not classified.Classification of the
substance or mixture
:
Signal word :No signal word.
Precautionary statements
Prevention :Not applicable.
Response :Not applicable.
Storage :Not applicable.
Disposal Not applicable.
GHS label elements
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
OSHA/HCS status :While this material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the
safe handling and proper use of the product. This SDS should be retained and available
for employees and other users of this product.
No known significant effects or critical hazards.:Hazard statements
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
birth defects or other reproductive harm.
:
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 1/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 2. Hazards identification
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
triethoxy(2,4,4-trimethylpentyl)silane ≤10 35435-21-3
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 2/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 4. First aid measures
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 3/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
triethoxy(2,4,4-trimethylpentyl)silane 35435-21-3 None.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits (OSHA United States)
Skin protection
None.
Ingredient name Exposure limits
Occupational exposure limits (Canada)
Environmental exposure
controls
:
None.
Exposure limits
Occupational exposure limits (Mexico)
CAS #
CAS #
CAS #
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 4/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.99
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
7.5
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :3.327 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Conditions to avoid No specific data.
The product is stable.Chemical stability :
:
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 5/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
No specific data.
:
Incompatible materials :
Section 11. Toxicological information
Acute toxicity
Not available.
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Not available.
Sensitization
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
Information on toxicological effects
Information on the likely
routes of exposure
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
:Not available.
Potential acute health effects
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 6/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Not available.
Toxicity
Not available.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 7/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
Not regulated.Not regulated.
--
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.No.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
Not regulated.
-
-
-
No.
-
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 8/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 1-Methyl-2-Pyrrolidone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause birth defects or other reproductive
harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
Section 16. Other information
11/27/2019
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:
:
:
:
Key to abbreviations :
11/27/2019
8/1/2019
4.01
Hazardous Material Information System (U.S.A.)
0
0
0
/Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
Not classified.
Procedure used to derive the classification
Classification Justification
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 9/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
Notice to reader
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Date of issue/Date of revision :11/27/2019 Date of previous issue :8/1/2019 Version :4.01 10/10
CF31T0007 ConFlex™ 7% Siloxane Water Repellent SHW-85-NA-GHS-US
102.10
SuperPaint® Exterior Latex Satin A89-100/1000 Series
SPECIFICATIONS
SuperPaint Exterior can be self-priming when used directly over existing coatings, or bare drywall, plaster and masonry (with a cured pH of less than 9). The first coat acts like a coat of primer and the second coat provides the final appearance and performance. Please note that some specific surfaces require specialized treatment.
Aluminum & Aluminum Siding1,
Galvanized Steel1, Vinyl Siding
2 cts. SuperPaint Exterior Latex
Concrete Block, CMU, Split face Block 1 ct. Loxon Acrylic Block Surfacer
2 cts. SuperPaint Exterior Latex
Brick
1 ct. Loxon Conditioner²
2 cts. SuperPaint Exterior Latex Cement Composition Siding/Panels
1 ct. Loxon Concrete & Masonry Primer2
or Loxon Conditioner²
2 cts. SuperPaint Exterior Latex
Stucco, Cement, Concrete
1 ct. Loxon Concrete & Masonry Primer2
2 cts. SuperPaint Exterior Latex
Plywood
1 ct. Exterior Latex Wood Primer
2 cts. SuperPaint Exterior Latex
Wood (Cedar, Redwood)3
1 ct. Exterior Oil-Based Wood Primer2
2 cts. SuperPaint Exterior Latex
1 On large expanses of metal siding, the air, surface, and material temperatures must be 50°F or higher. 2 Not for use at temperatures under 50°F. See specific primer label for that product’s application conditions. 3 Knots and some woods, such as redwood and cedar, contain a high amount of tannin, a colored wood extract. For best results on these woods, use a coat of Exterior Oil-Based Wood Primer. Other primers may be appropriate. Standard latex primers cannot be used below 50°F. See specific primer label for that product’s application conditions. When repainting involves a drastic color change, a coat of primer will improve the hiding performance of the topcoat color.
CHARACTERISTICS
SuperPaint Exterior, with resistance to early dirt pick up, provides outstanding performance on properly prepared aluminum and vinyl siding, wood, hardboard, masonry, cement, brick, block, stucco, and metal down to a surface and air temperature of 35°F. VinylSafe™ paint colors allow you the freedom to choose from 100 color options, including a limited selection of darker colors formulated to resist warping or buckling when applied to a sound, stable vinyl substrate.
Color: Most colors To optimize hide and color development, always use the recommended P-Shade primer Coverage: 350 - 400 sq ft/gal @ 4 mils wet; 1.5 mils dry
Drying Time, @ 50% RH: @ 35-45°F @ 45°F + Touch: 2 hour 2 hours Recoat: 24-48 hours 4 hours Drying and recoat times are temperature, humidity, and film thickness dependent Finish: 10-20 units @ 60°
Tinting with CCE:
Base oz/gal Strength
Extra White 0-6 SherColor
Deep Base 4-12 SherColor
Ultradeep Base 10-12 SherColor
Light Yellow 2-12 SherColor
Extra White A89W01151 (may vary by base) VOC (less exempt solvents): <50 g/L; <0.42 lb/gal As per 40 CFR 59.406 Volume Solids: 38 ± 2% Weight Solids: 49 ± 2% Weight per Gallon: 10.19 lb
Flash Point: N/A
Vehicle Type: 100% Acrylic Shelf Life: 36 months unopened WVP Perms (US) 26.14 grains/(hr ft2 in Hg)
Mildew Resistant This coating contains agents which inhibit the growth of mildew on the surface of this coating film.
05/2019 www.sherwin-williams.com continued on back
COMPLIANCE As of 05/29/2019, Complies with:
OTC Yes
OTC Phase II Yes
SCAQMD Yes CARB Yes CARB SCM 2007 Yes
Canada Yes
LEED® v4&v4.1 Emissons N/A
LEED® v4&v4.1 VOC Yes EPD-Certified N/A MIR-Certified N/A
MPI Yes
APPLICATION
When the air temperature is at 35°F, substrates may be colder; prior to painting, check to be sure the air, surface, and
material temperature are above 35°F and at least 5°F above the dew point. Avoid using if rain or snow is expected within 2-3
hours. Do not apply at air or surface temperatures below 35°F or when air or surface
temperatures may drop below 35°F within 48 hours. No reduction necessary.
Brush Use a nylon/polyester brush.
Roller Use a 3/8" - 3/4" nap synthetic cover.
Spray—Airless Pressure ..................................... 2000 psi
Tip ........................................ .015"-.019"
The information and recommendations set forth in this Product Data Sheet are based upon tests conducted by or on behalf of The Sherwin-Williams Company. Such information and recommendations set forth herein are subject to change and pertain to the product offered at the time of publication. Consult your Sherwin-Williams representative or visit www.paintdocs.com to obtain the most current version of the PDS and/or an SDS.
SuperPaint® Exterior Latex Satin
CAUTIONS For exterior use only. Protect from freezing. Non-photochemically reactive. Not for use on floors. Before using, carefully read CAUTIONS on label.
ZINC Use only with adequate ventilation. To avoid overexposure, open windows and doors or use other means to ensure fresh air entry during application and drying. If you experience eye watering, headaches, or dizziness, increase fresh air, or wear respiratory protection (NIOSH approved) or leave the area. Avoid contact with eyes and skin. Wash hands after using. Keep container closed when not in use. Do not transfer contents to other containers for storage. FIRST AID: In case of eye contact, flush thoroughly with large amounts of water. Get medical attention if irritation persists. If swallowed, call Poison Control Center, hospital emergency room, or physician immediately. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN. HOTW 05/28/2019 A89W01151 42 39 FRC,SP, KOR, Viet CLEANUP INFORMATION
Clean spills, spatters, hands and tools
immediately after use with soap and warm
water. After cleaning, flush spray equipment
with a compliant cleanup solvent to prevent
rusting of the equipment. Follow
manufacturer’s safety recommendations
when using solvents.
SURFACE PREPARATION
WARNING! Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. Remove all surface contamination by washing with an appropriate cleaner, rinse thoroughly and allow to dry. Scrape and sand peeled or checked paint to a sound surface. Sand glossy surfaces dull. Seal stains from water, smoke, ink, pencil, grease, etc. with the appropriate primer/sealer. Recognize that any surface preparation short of total removal of the old coating may compromise the service length of the system.
Aluminum and Galvanized Steel Wash to remove any oil, grease, or other surface contamination. All corrosion must be removed with sandpaper, wire brush, or other abrading method.
Caulking Gaps between windows, doors, trim, and other through-wall openings can be filled with the appropriate caulk after priming the surface. Cement Composition Siding/Panels Remove all dirt, dust, grease, oil, loose particles, laitance, foreign material, and peeling or defective coatings. Allow the surface to dry thoroughly. If the surface is new, test it for pH, if the pH is higher than 9, prime with Loxon Concrete & Masonry Primer.
Mildew Prior to attempting to remove mildew, it is always recommended to test any cleaner on a small, inconspicuous area prior to use. Bleach and bleaching type cleaners may damage or discolor existing paint films. Bleach alternative cleaning solutions may be advised. Mildew may be removed before painting by washing with a solution of 1 part liquid bleach and 3 parts water. Apply the solution and scrub the mildewed area. Allow the solution to remain on the surface for 10 minutes. Rinse thoroughly with water and allow the surface to dry before painting. Wear protective eyewear, waterproof gloves, and protective clothing. Quickly wash off any of the mixture that comes in contact with your skin. Do not add detergents or ammonia to the bleach/water solution.
SURFACE PREPARATION
Masonry, Concrete, Cement, Block All new surfaces must be cured according to the supplier’s recommendations—usually about 30 days. Remove all form release and curing agents. Rough surfaces can be filled to provide a smooth surface. If painting cannot wait 30 days, allow the surface to cure 7 days and prime the surface with Loxon Concrete & Masonry Primer. Cracks, voids, and other holes should be repaired with an elastomeric patch or sealant.
Steel Rust and mill scale must be removed using sandpaper, wire brush, or other abrading method. Bare steel must be primed the same day as cleaned.
Stucco Remove any loose stucco, efflorescence, or laitance. Allow new stucco to cure at least 30 days before painting. If painting cannot wait 30 days, allow the surface to dry 7 days and prime with Loxon Concrete & Masonry Primer. Repair cracks, voids, and other holes with an elastomeric patch or sealant. *Vinyl or other PVC Building Products Clean the surface thoroughly by scrubbing with warm, soapy water. Rinse thoroughly, prime with appropriate white primer. Do not paint vinyl with any color darker than the original color or having a Light Reflective Value (LRV) of less than 56 unless VinylSafe® Colors are used. If VinylSafe colors are not used the vinyl may warp. Follow all painting guidelines of the vinyl manufacturer when painting. Only paint properly installed vinyl siding. Deviating from the manufacturer's painting guidelines may cause the warranty to be voided. Wood, Plywood, Composition Board Clean the surface thoroughly then sand any exposed wood to a fresh surface. Patch all holes and imperfections with a wood filler or putty and sand smooth. All new and patched areas must be primed. Knots and some woods, such as redwood and cedar, contain a high amount of tannin, a colored wood extract. If applied to these bare woods, it may show some staining. If staining persists, spot prime severe areas with 1 coat of Exterior Oil-Based Wood Primer prior to using.
page 1 of 3
ENVIRONMENTAL DATA SHEET
(Certified Product Data Sheet)
43 00 [1589]
Date of Preparation
Nov 25, 2019
PRODUCT NUMBER
A89W1151
PRODUCT NAME
SUPERPAINT® Exterior Acrylic Latex Satin, Extra White
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
This document includes all data required by 40 CFR 63.801(a) for a Certified Product Data Sheet under criteria specified in 40 CFR 63.805(a).
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur
on individual batches due to adjustments made during production.
Hazard Category (for SARA 311.312)
A89W1151 = | Acute | Chronic |
Product Weight
10.19 lb/gal
Specific Gravity
1.23
FLASH POINT
N.A.
Volatile Ingredients
Chemical / Compound SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Water
7732-18-5 N N N N 50 61
Regulated Compounds
SARA 302 EHS CERCLA SARA 313 TC HAPS 112 % by Weight % by Volume
Zinc (as Zn)N Y Y N 2
Zinc Compound N N Y N 2
Volatile Organic Compounds - U.S. EPA / Canada
A89W1151
LB/Gal g/L
Coating Density 10.19 1220
By wt By vol
Total Volatiles 50.9%62.2%
Federally exempt solvents
Water 49.5%60.6%
Organic Volatiles 1.3%1.5%
Percent Non-Volatile 49.1%37.8%
VOC Content LB/Gal g/L
Total 0.12 15
Less exempt solvents 0.32 39
Of solids 0.34 40
Of solids 0.02 lb/lb 0.02 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per US EPA Aerosol Ctg Rule, MIR Values 2009) 0.03
A89W1151
page 2 of 3
Volatile Organic Compounds - California
A89W1151
LB/Gal g/L
Coating Density 10.19 1220
By wt By vol
Total Volatiles 50.9%62.2%
Exempt solvents
Water 49.5%60.6%
Organic Volatiles 1.3%1.5%
Percent Non-Volatile 49.1%37.8%
VOC Content LB/Gal g/L
Total 0.12 15
Less exempt solvents 0.32 39
Of solids 0.34 40
Of solids 0.02 lb/lb 0.02 kg/kg
By wt
By wt LVP-VOC 0.0%
Maximum Incremental Reactivity (MIR) (per California Air Resources Board Aerosol Products Regulation, MIR Values 2010) 0.02
Volatile Organic Compounds - South Coast Air Quality Management District, California, US
A89W1151
LB/Gal g/L
Coating Density 10.19 1220
By wt By vol
Total Volatiles 50.9%62.2%
Exempt solvents
Water 49.5%60.6%
Organic Volatiles 1.3%1.5%
Percent Non-Volatile 49.1%37.8%
VOC Content LB/Gal g/L
Total 0.12 15
Less exempt solvents 0.32 39
Of solids 0.34 40
Of solids 0.02 lb/lb 0.02 kg/kg
Volatile Organic Compounds - EU Directive 2004/42/EC
A89W1151
By wt By vol
Total Volatiles 51.2%62.6%
VOC Content LB/Gal g/L
Total 0.16 19
Volatile Organic Compounds - EU Directive 2010/75/EU
A89W1151
By wt By vol
Total Volatiles 50.5%61.7%
VOC Content LB/Gal g/L
Total 0.08 10
A89W1151
page 3 of 3
Volatile Organic Compounds - Mexico
A89W1151
LB/Gal g/L
Coating Density 10.19 1220
By wt By vol
Total Volatiles 50.9%62.2%
Exempt solvents
Water 49.5%60.6%
Organic Volatiles 1.3%1.5%
Percent Non-Volatile 49.1%37.8%
VOC Content LB/Gal g/L
Total 0.12 15
Less exempt solvents 0.32 39
Of solids 0.34 40
Of solids 0.02 lb/lb 0.02 kg/kg
Hazardous Air Pollutants (Clean Air Act, Section 112(b))
A89W1151
LB/Gal kg/L
Volatile HAPS 0.00 0.000
Of solids 0.00 0.000
Of solids 0.00 lb/lb 0.00 kg/kg
Air Quality Data
Density of Organic Solvent Blend
8.46 lb/gal
Photochemically Reactive
No
Additional Regulatory Information
US EPA TSCA:
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against:
Not Applicable
Waste Disposal
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
SUPERPAINT® Exterior Acrylic Latex Satin
Extra White
Not available.
Liquid.
US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer :THE SHERWIN-WILLIAMS COMPANY
101 W. Prospect Avenue
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
A89W1151
A89W1151Product code :
Product Information
Telephone Number
:US / Canada: 1-800-474-3794
Mexico: Not Available
Regulatory Information
Telephone Number
:US / Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:US / Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
CARCINOGENICITY - Category 2Classification of the
substance or mixture
:
Signal word :Warning
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity:
2.2%
Percentage of the mixture consisting of ingredient(s) of unknown acute dermal toxicity:
2.2%
Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation
toxicity: 2.2%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Suspected of causing cancer.:Hazard statements
Date of issue/Date of revision :11/27/2019 Date of previous issue :6/7/2019 Version :13 1/13
A89W1151 SUPERPAINT® Exterior Acrylic Latex Satin
Extra White
SHW-85-NA-GHS-US
Section 2. Hazards identification
Prevention :Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing.
Response :IF exposed or concerned: Get medical attention.
Storage :Store locked up.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General :Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Hazards not otherwise
classified
:None known.
Please refer to the SDS for additional information. Keep out of reach of children. Do not
transfer contents to other containers for storage.
Supplemental label
elements
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm.
:
Section 3. Composition/information on ingredients
Titanium Dioxide ≥10 - ≤25 13463-67-7
Zinc Oxide ≤3 1314-13-2
Heavy Paraffinic Oil ≤1 64742-65-0
Ingredient name CAS number% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
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Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders :If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. If during normal use the material presents a respiratory
hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
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Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 3/2019).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Zinc Oxide 1314-13-2 NIOSH REL (United States, 10/2016).
CEIL: 15 mg/m³ Form: Dust
TWA: 5 mg/m³ 10 hours. Form: Dust and
fumes
STEL: 10 mg/m³ 15 minutes. Form: Fume
OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours. Form: Fume
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
Heavy Paraffinic Oil 64742-65-0 OSHA PEL (United States, 5/2018).
TWA: 5 mg/m³ 8 hours.
ACGIH TLV (United States, 3/2019).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2016).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Titanium dioxide 13463-67-7 CA British Columbia Provincial (Canada,
5/2019).
TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 mg/m³ 8 hours. Form: Total dust.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 10 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 10 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.
Zinc Oxide 1314-13-2 CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 2 mg/m³ 8 hours. Form:
Respirable
15 min OEL: 10 mg/m³ 15 minutes. Form:
Respirable
CA British Columbia Provincial (Canada,
5/2019).
Ingredient name Exposure limits
Occupational exposure limits (Canada)
CAS #
CAS #
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Section 8. Exposure controls/personal protection
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
:
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
TWA: 2 mg/m³ 8 hours. Form: Respirable
STEL: 10 mg/m³ 15 minutes. Form:
Respirable
CA Ontario Provincial (Canada, 1/2018).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction.
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 5 mg/m³ 8 hours. Form: fume
STEV: 10 mg/m³ 15 minutes. Form: fume
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 10 mg/m³ 15 minutes. Form:
respirable dust and fume
TWA: 2 mg/m³ 8 hours. Form: respirable
dust and fume
Environmental exposure
controls
:
Zinc Oxide 1314-13-2 NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 2 mg/m³ 8 hours. Form: Respirable
fraction
STEL: 10 mg/m³ 15 minutes. Form:
Respirable fraction
Exposure limits
Occupational exposure limits (Mexico)
CAS #
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Section 8. Exposure controls/personal protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Respiratory protection :
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.22
1 [Air = 1]
2.3 kPa (17.5 mm Hg) [at 20°C]
Not available.
Not available.Odor
pH
Not available.Color
Evaporation rate 0.09 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: >94°C (>201.2°F)
Not available.
9
Viscosity Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point/boiling range :100°C (212°F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Decomposition temperature :Not available.
Heat of combustion :1.299 kJ/g
Aerosol product
Molecular weight :Not applicable.
Section 10. Stability and reactivity
Conditions to avoid No specific data.
The product is stable.Chemical stability :
:
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
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Section 10. Stability and reactivity
Hazardous decomposition
products
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
No specific data.
:
Incompatible materials :
Section 11. Toxicological information
Acute toxicity
Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human -72 hours 300
ug I
-
Zinc Oxide Eyes - Mild irritant Rabbit -24 hours 500
mg
-
Skin - Mild irritant Rabbit -24 hours 500
mg
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Name Result
Heavy Paraffinic Oil ASPIRATION HAZARD - Category 1
Information on toxicological effects
Classification
Titanium Dioxide -2B -
Product/ingredient name NTPIARCOSHA
Information on the likely
routes of exposure
:Not available.
Potential acute health effects
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Section 11. Toxicological information
Not available.
Inhalation :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact :No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects :Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects :Not available.
Section 12. Ecological information
Toxicity
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Zinc Oxide Acute IC50 1.85 mg/l Marine water Algae - Skeletonema costatum 96 hours
Acute IC50 46 µg/l Fresh water Algae - Pseudokirchneriella
subcapitata - Exponential growth
phase
72 hours
Acute LC50 98 µg/l Fresh water Daphnia - Daphnia magna -
Neonate
48 hours
Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Product/ingredient name SpeciesResult Exposure
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
Zinc Oxide -28960 high
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
Section 14. Transport information
-
-
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE,
LIQUID, N.O.S.
(Zinc Pyrithione,
Zinc Oxide).
Marine pollutant
(Zinc Pyrithione,
Zinc Oxide)
9
Not regulated.UN3082
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
TDG
Classification
Not regulated.
-
-
Mexico
Classification
Not regulated.
-
-
IATA
UN3082
ENVIRONMENTALLY
HAZARDOUS
SUBSTANCE,
LIQUID, N.O.S.
(Zinc Pyrithione,
Zinc Oxide)
9
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Section 14. Transport information
-III
-This product is not
regulated as a
dangerous good
when transported
in sizes of ≤5 L or
≤5 kg, provided
the packagings
meet the general
provisions of
4.1.1.1, 4.1.1.2
and 4.1.1.4 to
4.1.1.8.
Emergency
schedules F-A, S-
F
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.Yes.
Not available.
:
Proper shipping name :
Ship type :Not available.
Pollution category :Not available.
Not available.
:
-
No.
-
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
III
Yes.
This product is
not regulated as
a dangerous
good when
transported in
sizes of ≤5 L or
≤5 kg, provided
the packagings
meet the general
provisions of
5.0.2.4.1,
5.0.2.6.1.1 and
5.0.2.8.
Section 15. Regulatory information
SARA 313
TSCA 5(a)2 proposed significant new use rules: 5-Chloro-2-methylisothiazolinone
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS): Not determined.
China inventory (IECSC): Not determined.
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Korea inventory (KECI): Not determined.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): Not determined.
Taiwan Chemical Substances Inventory (TCSI): Not determined.
Thailand inventory: Not determined.
Turkey inventory: Not determined.
Vietnam inventory: Not determined.
International regulations
International lists :
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Section 16. Other information
11/27/2019
History
Date of printing
Date of issue/Date of
revision
Version
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
Key to abbreviations :
11/27/2019
6/7/2019
13
Hazardous Material Information System (U.S.A.)
1
0
0
*Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
CARCINOGENICITY - Category 2 Calculation method
Procedure used to derive the classification
Classification Justification
Notice to reader
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
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Section 16. Other information
obtained from any other source.
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